Heterometallic copper(Ⅱ) vanadates: synthesis, crystal structures and third-order nonlinear optical properties
文献类型:CNKI期刊论文
作者 | LIU FaQian; WANG Lei; GUO JiXi; LI WeiHua; LI ChaoQin; JIN YanLing; LI RongXun; JIAN FangFang |
发表日期 | 2014-09-01 |
出处 | Science China(Chemistry)
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关键词 | cluster polymers,third-order nonlinear optical properties,TD-DFT calculations,polyoxovanadate |
英文摘要 | Three polymeric heterometallic clusters with 1D, 2D, and 3D frameworks, constructed from a cyclic vanadate {V4O12}4-building block and three geometric constraint ligands, were synthesized by a one-pot self-assembly reaction. Z-scan experiments demonstrated that all the three cluster polymers have large hyperpolarizability γ values. TD-DFT calculations afforded insight into the electronic transitions and spectral characterization of these novel NLO molecular materials. |
文献子类 | CNKI期刊论文 |
资助机构 | supported by the National Natural Science Foundation of China(21371105,51372125) ; the Natural Science Foundation of Shandong Province(2009ZRA02071) ; the Scientific Development Plan of University in Shandong Province(J09LB53) ; the Doctoral Science Foundation of QUST |
卷 | v.57期:09页:59-69 |
语种 | 英文; |
分类号 | O631.2 |
ISSN号 | 1674-7291 |
源URL | [http://ir.qdio.ac.cn/handle/337002/190338] ![]() |
专题 | 中国科学院海洋研究所 |
作者单位 | 1.CollaborativeInnovationCenterofEngineeringConstructionandSafetyforOceanicEconomicZone 2.EngineeringResearchCenterofHighPerformancePolymer&MoldingTechnology,MinistryofEducation,QingdaoUniversityofScienceandTechnology 3.InstituteofAppliedChemistry,XinjiangUniversity 4.InstituteofOceanology,ChineseAcademyofSciences |
推荐引用方式 GB/T 7714 | LIU FaQian,WANG Lei,GUO JiXi,et al. Heterometallic copper(Ⅱ) vanadates: synthesis, crystal structures and third-order nonlinear optical properties. 2014. |
入库方式: OAI收割
来源:海洋研究所
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