A mechanically robust superhydrophobic corrosion resistant coating with self-healing capability
文献类型:期刊论文
作者 | Sun, Jizhou1,2,3; Wang, Jian4; Xu, Weichen2,3; Zhang, Binbin2,3![]() |
刊名 | MATERIALS & DESIGN
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出版日期 | 2024-04-01 |
卷号 | 240页码:12 |
关键词 | Superhydrophobic Self-healing Anti-corrosion Self-cleaning Robust |
ISSN号 | 0264-1275 |
DOI | 10.1016/j.matdes.2024.112881 |
通讯作者 | Zhang, Binbin(zhangbinbin11@mails.ucas.ac.cn) |
英文摘要 | Conferring self-healing capability represents an effective approach for extending the lifespan of multifunctional superhydrophobic coatings. Presently, reported self-healing superhydrophobic coatings exhibit scratch-healing capabilities ranging from 5 mu m to 40 mu m. However, achieving large-scale scratch-healing (>100 mu m) remains a significant challenge within this research domain. In this paper, we introduces the design and fabrication of a dual-layer self-healing superhydrophobic anti-corrosion coating using polycaprolactone (PCL), EASTMAN Kristalex 3085 resin (EK), epoxy resin (EP), and 1H, 1H, 2H, 2H-perfluorodecyltriethoxysilane (PFDTES) modified silica particles via a facile spray-coating approach. The surface morphology, chemical composition, wettability, self-cleaning, damage-healing, and anti-corrosion behaviors of the coating were thoroughly evaluated. Results demonstrate that the coating exhibits self-healing capabilities across multiple scratch-damage scales (45 mu m, 55 mu m, and 100 mu m), particularly exhibiting superior large-scale scratch-healing ability. Furthermore, the coating displays outstanding corrosion resistance, with the charge transfer resistance (R-ct) increasing by nearly 8 orders of magnitude compared to the bare Q235 carbon steel substrate. Although the corrosion resistance of the scratch- damaged coatings significantly decreases, the anti-corrosion capability of the scratch-healed coating is effectively restored to its initial state, showcasing excellent anti-corrosion sustainability. Additionally, the coating demonstrates remarkable mechanical stability, withstanding 90 sandpaper abrasion cycles and 70 tape-peeling cycles. |
WOS关键词 | SILICA NANOPARTICLES ; PROTECTION ; MEMBRANE ; SURFACES ; DESIGN ; ALLOY |
资助项目 | Shandong Pro-vincial Natural Science Foundation[ZR2022YQ35] ; Shandong Pro-vincial Natural Science Foundation[ZR2021LFG004] ; Youth Innovation Promotion Association of Chinese Academy of Sciences[2021207] |
WOS研究方向 | Materials Science |
语种 | 英语 |
WOS记录号 | WOS:001300443800001 |
出版者 | ELSEVIER SCI LTD |
源URL | [http://ir.qdio.ac.cn/handle/337002/198158] ![]() |
专题 | 海洋研究所_海洋腐蚀与防护研究发展中心 |
通讯作者 | Zhang, Binbin |
作者单位 | 1.Qingdao Univ, Coll Mech & Elect Engn, Qingdao 266071, Peoples R China 2.Chinese Acad Sci, Inst Oceanol, CAS Key Lab Marine Environm Corros & Biofouling, Qingdao 266071, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.Tokyo Inst Technol, Sch Mat & Chem Technol, Dept Mat Sci & Engn, Tokyo 1528552, Japan |
推荐引用方式 GB/T 7714 | Sun, Jizhou,Wang, Jian,Xu, Weichen,et al. A mechanically robust superhydrophobic corrosion resistant coating with self-healing capability[J]. MATERIALS & DESIGN,2024,240:12. |
APA | Sun, Jizhou,Wang, Jian,Xu, Weichen,&Zhang, Binbin.(2024).A mechanically robust superhydrophobic corrosion resistant coating with self-healing capability.MATERIALS & DESIGN,240,12. |
MLA | Sun, Jizhou,et al."A mechanically robust superhydrophobic corrosion resistant coating with self-healing capability".MATERIALS & DESIGN 240(2024):12. |
入库方式: OAI收割
来源:海洋研究所
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