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Metamorphic origin of large nuggets of platinum-group metals: evidence from multiphase inclusions in Os-Ir-Ru alloys from the Adamsfield placer, Tasmania

文献类型:期刊论文

作者Kutyrev, Anton11; Kamenetsky, Vadim S.9,10; Chayka, Ivan F.8; Nekrylov, Nikolai A.7; Kryuchkova, Lyudmila6; Shilovskikh, Vladimir V.5; Kontonikas-Charos, Alkiviadis4; Krasheninnikov, Stepan P.3; Sapegina, Anna1,2,8; Perchuk, Alexei L.1,2,8
刊名JOURNAL OF PETROLOGY
出版日期2024-08-21
卷号65期号:8页码:12
关键词ophiolite osmium chromitite melt inclusions platinum-group elements
ISSN号0022-3530
DOI10.1093/petrology/egae086
通讯作者Kutyrev, Anton(KutyrevA@cardiff.ac.uk)
英文摘要Platinum-group elements (PGE) are most effectively concentrated via sulfide-silicate melt immiscibility; however, under sulfide-undersaturated conditions, PGE may exhibit highly siderophile behavior and occur as native metals and alloys. In this case, they can form micrometer-size inclusions within Cr-spinel, but also large nuggets (up to several kilograms), found in chromitites and related placer deposits. The exact formation mechanism of such large nuggets and accumulations of PGE unrelated to sulfide melts remains controversial due to mass balance issues. In this study of multiphase inclusions in Os-Ir-Ru nuggets from the Adamsfield placer district (Tasmania, Australia), we constrain their crystallization environment. Multiphase inclusions comprise variable proportions of hornblende, enstatite, quartz, anthophyllite, anorthite, chlorite and native iridium and coexist with single-phase olivine and Cr-spinel inclusions. The heterogeneity in phase and chemical composition of the inclusions indicates a complex origin from an inhomogeneous source media. This is corroborated by grain scale disequilibrium mineral assemblages, where forsterite and quartz are both included within a single osmium grain. Our proposed multi-stage origin of Adamsfield Os-Ir-Ru nuggets involved magmatic olivine-Cr-spinel-Os-Ir-Ru cumulates in peridotite bodies that were subsequently overprinted by various hydrothermal and metamorphic processes, including serpentinization or growth of Os-Ir-Ru from supercritical fluids. The final metamorphic stage resulted in the obliteration of Os-Ir-Ru zonation, culminating in the current assemblage of inclusions.
WOS关键词HIGHLY-SIDEROPHILE ELEMENTS ; GROUP MINERALS ; OMAN OPHIOLITE ; SULFIDE LIQUID ; NIZHNY-TAGIL ; CR-SPINEL ; CHROMITITES ; SILICATE ; FRACTIONATION ; COMPLEX
资助项目Visiting Scientist Award by the Chinese Academy of Sciences ; D.S. Korzhinskii Institute of Experimental Mineralogy RAS (I.F.C.)[FMUF-2022-0004]
WOS研究方向Geochemistry & Geophysics
语种英语
WOS记录号WOS:001295031900001
出版者OXFORD UNIV PRESS
源URL[http://ir.qdio.ac.cn/handle/337002/198074]  
专题海洋研究所_深海极端环境与生命过程研究中心
通讯作者Kutyrev, Anton
作者单位1.RAS, Korzhinskii Inst Expt Mineral, Lab Lithosphere Metamorphism Magmatism & Geodynam, 4 Academician Ossipyanstr, Chernogolovka 142432, Russia
2.Moscow MV Lomonosov State Univ, Fac Geol, Dept Petrol & Volcanol, Leninskie Gori 1, Moscow 119991, Russia
3.RAS, Vernadsky Inst Geochem & Analyt Chem, Lab Geochem Igneous & Metamorph Rocks, 19 Kosygina str, Moscow 119991, Russia
4.Queensland Univ Technol, Sch Earth & Atmospher Sci, P Block,Level 6,Gardens Point Rd, Brisbane, Qld 4001, Australia
5.St Petersburg State Univ, Geomodel Ctr, Ulyanovskaya str 1, St Petersburg 198504, Russia
6.St Petersburg State Univ, Ctr X Ray Diffract Studies, Res Pk, Decabristov lane 16, St Petersburg 199155, Russia
7.Inst Geol Sci NAS RA, Lab Volcanol, Marshal Baghramyan Ave 24, Yerevan, Armenia
8.Korzhinskii Inst Expt Mineral RAS, Lab Physiochem Problems Magmatism, 4 Academician Ossipyan Str, Chernogolovka 142432, Russia
9.Inst Volcanol & Seismol FEB RAS, Lab Mineral, Piipa 9, Petropavlovsk Kamchatski 683006, Russia
10.Chinese Acad Sci, Ctr Deep Sea Res, Inst Oceanol, 7 Nanhai Rd, Qingdao 266071, Peoples R China
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Kutyrev, Anton,Kamenetsky, Vadim S.,Chayka, Ivan F.,et al. Metamorphic origin of large nuggets of platinum-group metals: evidence from multiphase inclusions in Os-Ir-Ru alloys from the Adamsfield placer, Tasmania[J]. JOURNAL OF PETROLOGY,2024,65(8):12.
APA Kutyrev, Anton.,Kamenetsky, Vadim S..,Chayka, Ivan F..,Nekrylov, Nikolai A..,Kryuchkova, Lyudmila.,...&Perchuk, Alexei L..(2024).Metamorphic origin of large nuggets of platinum-group metals: evidence from multiphase inclusions in Os-Ir-Ru alloys from the Adamsfield placer, Tasmania.JOURNAL OF PETROLOGY,65(8),12.
MLA Kutyrev, Anton,et al."Metamorphic origin of large nuggets of platinum-group metals: evidence from multiphase inclusions in Os-Ir-Ru alloys from the Adamsfield placer, Tasmania".JOURNAL OF PETROLOGY 65.8(2024):12.

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来源:海洋研究所

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