The influence of silica on reaction rates and molecular hydrogen (H2) generation during olivine hydrothermal alteration
文献类型：期刊论文
| 作者 | Huang, Ruifang4,5; Sun, Weidong3 ; Ding, Xing2; Zhao, Yusheng5; Li, Yibing1; Shang, Xiuqi4
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| 刊名 | SCIENCE CHINA-EARTH SCIENCES
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| 出版日期 | 2024 |
| 卷号 | 67期号:1页码:222-233 |
| 关键词 | Olivine hydrothermal alteration Silica Serpentinization Hydrogen Serpentine |
| ISSN号 | 1674-7313 |
| DOI | 10.1007/s11430-023-1172-9 |
| 通讯作者 | Huang, Ruifang(huangrf@sustech.edu.cn) |
| 英文摘要 | Hydrothermal alteration of olivine greatly influences geodynamics and the recycling of volatiles (such as water and carbon) in subduction zones. Silica is an important component of geological fluids, and its influence on the hydrothermal alteration of olivine remains poorly constrained. In this study, we performed experiments at 300-515(degrees)C and 3.0 kbar (1 bar=10(5) Pa) by reacting well homogenized mixtures of olivine and silica powders with saline solutions (0.5 mol L-1 NaCl). Silica greatly influences the reaction pathways, reaction rates, and molecular hydrogen (H-2) formation during olivine hydrothermal alteration. In experiments at 300(degrees)C and 3.0 kbar with mixtures of olivine and 10 wt% silica, olivine was replaced by serpentine and talc. The proportions of serpentine and talc were determined according to standard curves based on infrared spectroscopy analyses. Around 6.5% serpentine and 12% talc were produced after an experimental duration of 7 days, which had no change after a longer period (14 days). Compared to the kinetics in silica-free systems, the rates of olivine hydrothermal alteration in experiments with 10 wt% silica are much lower. The overall reaction is: 4.5Forsterite+5.5SiO(2,aq)+4H(2)O=Serpentine+2Talc. With the addition of more silica (20 wt% and 40 wt%), olivine was transformed into talc. The rates of reaction were much faster, e.g., for experiments with olivine and 20 wt% silica, 43% of talc was produced after 14 days, which increased to 77% for experiments with 40 wt% silica over the same period. The overall reaction is: 3Forsterite+5SiO(2,aq)+2H(2)O=2Talc. In experiments at 400-505(degrees)C and 3.0 kbar, the promoting effect of silica on olivine hydrothermal alteration was also observed, which is closely associated with a decrease in Gibbs free energies of olivine hydrothermal alteration. At 300(degrees)C and 3.0 kbar, silica decreased H(2 )formed during olivine hydrothermal alteration by around an order of magnitude, resulting in an increase in oxygen fugacity. Based on measured H-2, we calibrated oxygen fugacities, ranging from 0.96 to 3.41 log units below FMQ (fayalite-magnetite-quartz buffer assemblage). This study suggests that the infiltration of SiO2-bearing fluids into peridotites greatly influences redox conditions and the rates of olivine hydrothermal alteration. |
| WOS关键词 | MID-ATLANTIC RIDGE ; 300 DEGREES-C ; ABYSSAL PERIDOTITES ; EXPERIMENTAL SERPENTINIZATION ; HYDRATION REACTIONS ; ULTRAMAFIC ROCKS ; TRACE-ELEMENT ; VENT FLUIDS ; MANTLE ; FIELD |
| 资助项目 | National Natural Science Foundation of China[41873069] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA22050103] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDB42000000] ; Shenzhen Municipal Natural Science Foundation[JCYJ20220530113016038] |
| WOS研究方向 | Geology |
| 语种 | 英语 |
| WOS记录号 | WOS:001127229400002 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://ir.qdio.ac.cn/handle/337002/199638]  |
| 专题 | 海洋研究所_深海极端环境与生命过程研究中心 |
| 通讯作者 | Huang, Ruifang |
| 作者单位 | 1.Chinese Acad Geol Sci, Institue Geol, Beijing 100037, Peoples R China 2.Chinese Acad Sci, State Key Lab Isotope Geochem, Guangzhou Inst Geochem, Guangzhou 510640, Peoples R China 3.Chinese Acad Sci, Ctr Deep Sea Res, Inst Oceanol, Qingdao 266071, Peoples R China 4.Southern Univ Sci & Technol SUSTech, Acad Adv Interdisciplinary Studies, Shenzhen 518055, Peoples R China 5.Chinese Acad Sci, South China Sea Inst Oceanol, CAS Key Lab Ocean & Marginal Sea Geol, Guangzhou 510301, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, Ruifang,Sun, Weidong,Ding, Xing,et al. The influence of silica on reaction rates and molecular hydrogen (H2) generation during olivine hydrothermal alteration[J]. SCIENCE CHINA-EARTH SCIENCES,2024,67(1):222-233. |
| APA | Huang, Ruifang,Sun, Weidong,Ding, Xing,Zhao, Yusheng,Li, Yibing,&Shang, Xiuqi.(2024).The influence of silica on reaction rates and molecular hydrogen (H2) generation during olivine hydrothermal alteration.SCIENCE CHINA-EARTH SCIENCES,67(1),222-233. |
| MLA | Huang, Ruifang,et al."The influence of silica on reaction rates and molecular hydrogen (H2) generation during olivine hydrothermal alteration".SCIENCE CHINA-EARTH SCIENCES 67.1(2024):222-233. |
入库方式： OAI收割
来源：海洋研究所
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