Catalytic conversion of CO₂ to valuable products is a promising way to reduce anthropogenic CO₂ emission. Herein, a strategy for coupling conversion of CO₂ and high-carbon alkane to CO and gasoline is developed, which is a feasible choice for the combination of CO₂ recycling and petroleum refining. The CO₂ conversion reaches 2.6% under mild condition (270 °C), and the selectivity of gasoline in the cracking products exceeds 70 wt%. Additionally, the introduction of CO₂ improves the selectivity of aromatic hydrocarbons and increases the octane number of gasoline. Mechanism studies indicate that synergistic effect between Brønsted acid centers and Ni sites on the Beta zeolite supported Ni (20 wt%) catalyst (20Ni/β) plays the key role in alkane cracking and CO₂ reduction. Notably, ¹³CO₂ isotopic experiments show that the hydrogen produced during the aromatization can be captured by CO₂, inhibiting undesired hydrogen transfer pathways and enhanced the yield of aromatics, while CO₂ is converted into valuable CO.