Quasi-metallic high-entropy spinel oxides for full-spectrum solar energy harvesting
文献类型:期刊论文
作者 | Baohua Liu2,3![]() ![]() ![]() ![]() |
刊名 | Matter
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出版日期 | 2024-01 |
卷号 | 7期号:1页码:140-157 |
DOI | 10.1016/j.matt.2023.10.020 |
英文摘要 | Broadband absorbers, capable of efficiently capturing solar energy across the full spectrum, are highly desired for solar-thermal applications. Here, we developed such an absorber by marriage of a high-entropy strategy and the prevailing spinel oxides. A high-entropy spinel oxide (CoCrFeMnNi)3O4 is synthesized by a facile sol-gel combustion approach. This high-entropy engineering narrows the band gap of the spinel oxide from 2.65 eV to 0 eV, showing a quasi-metallic characteristic. Notably, it reaches the lower limit for band gaps (0 eV) of spinel oxides, which has not been realized previously to the best of our knowledge. As a result, it leads to an impressive solar absorptance of 95.5% across the entire solar spectrum. As a proof of concept, we experimentally demonstrate its appealing potential in solar water evaporation, achieving an excellent evaporation efficiency of 96.5%. Our findings provide an avenue for the development of high-performance solar absorbers for high-efficiency solar-thermal conversion systems. |
语种 | 英语 |
源URL | [http://ir.licp.cn/handle/362003/30660] ![]() |
专题 | 兰州化学物理研究所_环境材料与生态化学研究发展中心 |
通讯作者 | Baohua Liu; Yang Li |
作者单位 | 1.State Key Laboratory of Hydrology-Water Resources and Hydraulic Engineering, Hohai University, Nanjing 210098, China 2.Laboratory of Clean Energy Chemistry and Materials, State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China 3.Center of Materials Science and Optoelectronics Engineering, University of the Chinese Academy of Sciences, Beijing 100049, China 4.State Key Laboratory of Fluid Power and Mechatronic Systems, School of Mechanical Engineering, Zhejiang University, Hangzhou 310027, China 5.Key Laboratory of Advanced Manufacturing Technology of Zhejiang Province, School of Mechanical Engineering, Zhejiang University, Hangzhou 310027, China |
推荐引用方式 GB/T 7714 | Baohua Liu,Chengyu He,Yang Li,et al. Quasi-metallic high-entropy spinel oxides for full-spectrum solar energy harvesting[J]. Matter,2024,7(1):140-157. |
APA | Baohua Liu.,Chengyu He.,Yang Li.,Zhengtong Li.,Weiming Wang.,...&Gao XH.(2024).Quasi-metallic high-entropy spinel oxides for full-spectrum solar energy harvesting.Matter,7(1),140-157. |
MLA | Baohua Liu,et al."Quasi-metallic high-entropy spinel oxides for full-spectrum solar energy harvesting".Matter 7.1(2024):140-157. |
入库方式: OAI收割
来源:兰州化学物理研究所
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