Superamphiphobic coatings have good application prospects in many fields but are limited by their low impalement resistance, weak mechanical stability, and easy adhesion of tiny droplets. Here, impalement-resistant, mechanically stable, and antistatic super-amphiphobic coatings were fabricated by spraying a mixture of conductive carbon black (CB), silicone-modified polyester adhesive/fluorinated SiO₂ microspheres onto Al alloy. Themicrospheres were obtained by adhesive phase separation and the binding of fluorinated SiO₂ to them. The morphology, superamphiphobicity, impalement resistance, and mechanical stability of the coatings could be regulated by using solvents with different boiling points. As an result, the coatings simultaneously exhibited outstanding mechanical stability, impalement resistance, and superamphiphobicity. The addition of conductive CB endowed the coatings with good antistatic and tiny droplet repellent properties. In addition, the coatings exhibited good anti-icing properties due to the steady air layer at the solid−liquid interface and the very small contact area between them. We suppose that the coatings are very promising for practical application in various fields, including anti-icing, due to their outstanding comprehensive properties and simple preparation process.