Reaction kinetics and molecular characterization of the compounds formed by photosensitized degradation of the plastic additive bisphenol A in the atmospheric aqueous phase
文献类型：期刊论文
| 作者 | Wang, Yiting2; Deng, Qingxin5,6,7,9,10; Wang, Yiqun5,6,7,9,10; Li, Pan5,6,7,9,10; Jin, Biao5,6,7,9 ; Liu, Jiangping1; Cheng, Peng4; Brigante, Marcello4; D'Antuono, Dario3; Carena, Luca3
|
| 刊名 | SCIENTIFIC REPORTS
 |
| 出版日期 | 2024-12-30 |
| 卷号 | 14期号:1页码:12 |
| 关键词 | Photochemistry Bisphenols Aromatic compounds Sea surface Aerosols Clouds |
| ISSN号 | 2045-2322 |
| DOI | 10.1038/s41598-024-82865-y |
| 英文摘要 | Bisphenol A (BPA, 4,4'-(propane-2,2-diyl)diphenol) is a common plasticizer that is very widespread in the environment and is also found at significant concentrations in the global oceans, due to contamination by plastics. Here we show that triplet sensitization is an important degradation pathway for BPA in natural surface waters, which could prevail if the water dissolved organic carbon is above 2-3 mgC L-1. Bromide levels as per seawater conditions have the potential to slow down BPA photodegradation, a phenomenon that could not be offset by reaction of BPA with Br2 center dot- (second-order reaction rate constant of (2.54 +/- 0.09) x 108 M-1 s-1). Ultra-high resolution mass spectrometry revealed that the presence of inorganic salts (NaCl and NaBr) markedly increased the complexity of the observed CHO product compounds formed upon photosensitized degradation of BPA. The obtained results suggest that bisphenols can be efficiently removed by photosensitized reactions and generate higher number of oligomers and polyaromatic compounds in the sea surface and liquid water of marine aerosols compared to freshwaters and/or dilute cloud-water. Considering that polyaromatic compounds absorb solar actinic radiation, these results suggest that inorganic salts could significantly affect the photosensitized degradation of bisphenols and consequently influence the light-absorbing properties of marine aerosols and, ultimately, the Earth's radiative balance. |
| WOS研究方向 | Science & Technology - Other Topics |
| 语种 | 英语 |
| WOS记录号 | WOS:001386372700005 |
| 源URL | [http://ir.gig.ac.cn/handle/344008/81812]  |
| 专题 | 有机地球化学国家重点实验室 |
| 通讯作者 | Chen, Hui; Vione, Davide; Gligorovski, Sasho |
| 作者单位 | 1.Kunming Univ Sci & Technol, Fac Environm Sci & Engn, Kunming 650500, Peoples R China 2.Shanghai Univ, Sch Environm & Chem Engn, Key Lab Organ Cpd Pollut Control Engn, Shanghai 200444, Peoples R China 3.Univ Torino, Dipartimento Chim, Via Pietro Giuria 5, I-10125 Turin, Italy 4.Univ Clermont Auvergne, Inst Chim Clermont Ferrand, CNRS, F-63000 Clermont Ferrand, France 5.Chinese Acad Sci, Guangzhou Inst Geochem, State Key Lab Organ Geochem, Guangzhou 510640, Peoples R China 6.Chinese Acad Sci, Guangzhou Inst Geochem, Guangdong Prov Key Lab Environm Protect & Resource, Guangzhou 510640, Peoples R China 7.Chinese Acad Sci, Guangzhou Inst Geochem, Guangdong Hong Kong Macao Joint Lab Environm Pollu, Hong Kong 510640, Guangdong, Peoples R China 8.Univ St Kliment Ohridski Bitola, Fac Informat & Commun Technol Bitola, Bvd 1st May B B, Bitola 7000, North Macedonia 9.Chinese Acad Sci, Ctr Excellence Deep Earth Sci, Guangzhou 510640, Peoples R China 10.Univ Chinese Acad Sci, Beijing 101408, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Yiting,Deng, Qingxin,Wang, Yiqun,et al. Reaction kinetics and molecular characterization of the compounds formed by photosensitized degradation of the plastic additive bisphenol A in the atmospheric aqueous phase[J]. SCIENTIFIC REPORTS,2024,14(1):12. |
| APA | Wang, Yiting.,Deng, Qingxin.,Wang, Yiqun.,Li, Pan.,Jin, Biao.,...&Gligorovski, Sasho.(2024).Reaction kinetics and molecular characterization of the compounds formed by photosensitized degradation of the plastic additive bisphenol A in the atmospheric aqueous phase.SCIENTIFIC REPORTS,14(1),12. |
| MLA | Wang, Yiting,et al."Reaction kinetics and molecular characterization of the compounds formed by photosensitized degradation of the plastic additive bisphenol A in the atmospheric aqueous phase".SCIENTIFIC REPORTS 14.1(2024):12. |
入库方式： OAI收割
来源：广州地球化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。