To investigate the feasibility of using temperature for tracking rainfall-runoff processes in karst catchments, this study developed a tracer-aided conceptual model using temperature as a tracer by coupling water and heat transport processes at the catchment scale. The model was calibrated and validated using hourly hydrometeorological and temperature data from a 1.25 km² karst catchment in south-western China. The results showed that the model was able to capture the water flux and temperature dynamics of different landscape units in the karst catchment. Utilizing this framework, the model delineated the flux age distribution within different landscape units, as well as the overall water transit times through the catchment. The average flux ages were determined to be approximately 80 days for the hillslope unit, 452 days for the slow flow system, and 260 days for the fast flow regime within the depression areas. These estimations align broadly with those acquired using stable isotopes as tracers. Comparative analysis revealed that the flux age distributions derived from both temperature and isotopic tracers exhibited analogous patterns at the catchment outlet and across the hillslope compartments. However, the simulations based on temperature hinted at a heightened proportion of exceedingly young and decidedly old water in the outflow, alluding to a potential overestimation of these extreme age classes by the temperature-tracer model. From the temperature-simulated transit time distribution, about 31 % of the precipitation entering during the study period have left the catchment within 3 years, and a notable proportion of rain water was either stored in the aquifer or lost through evapotranspiration. The general characteristics of the transit time distribution simulated using temperature was similar with that simulated using isotopes, though a higher proportion of precipitation being drained by fast flows was inferred from the transit time distribution simulated using temperature. Collectively, our study demonstrated that temperature can serve as a cost-effective tracer for modelling of water age distributions and associated hydrological processes in karst catchments.