Efficient preconcentration of ultra-trace rhenium from geological materials via induced adsorption for accurate isotope analysis
文献类型：期刊论文
| 作者 | Liu, Yumeng1; Chen, Tianyu1; Li, Tao2; Li, Weiqiang1; Hong, Qingquan1; Chen, Jiubin3 |
| 刊名 | JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY
 |
| 出版日期 | 2024-09-30 |
| 页码 | 8 |
| ISSN号 | 0267-9477 |
| DOI | 10.1039/d4ja00295d |
| 通讯作者 | Chen, Tianyu(tianyuchen@nju.edu.cn) |
| 英文摘要 | Rhenium (Re) and its isotopes offer valuable information for understanding various geological processes throughout Earth's history. However, Re isotope analysis remains quite challenging owing to its ultra-trace concentration in geological materials. Previous studies have developed column chemistry and analytical methods for Re isotope analysis, but issues such as tedious pretreatment and incomplete Re recovery still exist. Herein, we present a novel procedure integrating preconcentration and fast column chemistry for Re isotope analysis. Utilizing Na2S solution and activated carbon powder under acidified conditions, we achieved the quantitative recovery of Re from aqueous solutions via filtration while removing most matrices. Standard addition to diverse matrix solutions yielded complete Re recovery (99.6 +/- 6.7%, n = 10, 2SD) and precise isotopic compositions (delta Re-187 = -0.49 +/- 0.04 parts per thousand, n = 10, 2SD), as determined using multi-collector inductively coupled plasma-mass spectrometry. Our method was applied to seawater (7.1 pg g(-1) for Re) and solid reference materials (similar to 0.5-75 ng g(-1) for Re), which resulted in stable and high recovery with isotopic results consistent with published data. Our method exhibits efficient matrix removal with stable and essentially quantitative Re recovery, which paves the way for wide applications of Re isotopes in the earth and planetary sciences. |
| WOS关键词 | INTERSPECIES ELECTRON-TRANSFER ; COMPARATIVE GEOCHEMISTRY ; COPRECIPITATION METHOD ; TUNGSTEN SPECIATION ; SULFIDIC WATERS ; MOLYBDENUM ; CARBON ; SEQUESTRATION ; CHALCOPHILE ; ENRICHMENTS |
| 资助项目 | National Natural Science Foundation of China[42361144845] ; National Natural Science Foundation of China[92358301] ; National Natural Science Foundation of China[41991325] ; National Natural Science Foundation of China |
| WOS研究方向 | Chemistry ; Spectroscopy |
| 语种 | 英语 |
| WOS记录号 | WOS:001325094000001 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 资助机构 | National Natural Science Foundation of China ; National Natural Science Foundation of China |
| 源URL | [http://ir.nigpas.ac.cn/handle/332004/44361]  |
| 专题 | 中国科学院南京地质古生物研究所 |
| 通讯作者 | Chen, Tianyu |
| 作者单位 | 1.Nanjing Univ, Frontiers Sci Ctr Crit Earth Mat Cycling, Sch Earth Sci & Engn, State Key Lab Mineral Deposits Res, Nanjing 210046, Peoples R China 2.Chinese Acad Sci, State Key Lab Palaeobiol & Stratig, Nanjing Inst Geol & Palaeontol, Nanjing 210008, Peoples R China 3.Tianjin Univ, Inst Surface Earth Syst Sci, Sch Earth Syst Sci, Tianjin 300072, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Yumeng,Chen, Tianyu,Li, Tao,et al. Efficient preconcentration of ultra-trace rhenium from geological materials via induced adsorption for accurate isotope analysis[J]. JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY,2024:8. |
| APA | Liu, Yumeng,Chen, Tianyu,Li, Tao,Li, Weiqiang,Hong, Qingquan,&Chen, Jiubin.(2024).Efficient preconcentration of ultra-trace rhenium from geological materials via induced adsorption for accurate isotope analysis.JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY,8. |
| MLA | Liu, Yumeng,et al."Efficient preconcentration of ultra-trace rhenium from geological materials via induced adsorption for accurate isotope analysis".JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY (2024):8. |
入库方式： OAI收割
来源：南京地质古生物研究所
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