Atomic Insights into the Heterogeneous Crystallization of Manganese (Oxyhydr)oxides on Typical Iron (Oxyhydr)oxides: from Adsorption to Oxidation to Crystallization
文献类型：期刊论文
| 作者 | Tong, Shouhao7,8,9; Wei, Hongyan5,6; Zhou, Junming4; Yang, Yixuan5,6; Zhu, Runliang5,6 ; Chen, Qingze5,6; Xie, Xiande3; Hu, Qing8,9; Hochella Jr, Michael F.1,2; Liu, Jing8,9
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| 刊名 | ENVIRONMENTAL SCIENCE & TECHNOLOGY
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| 出版日期 | 2025-02-20 |
| 卷号 | 59期号:8页码:3961-3971 |
| 关键词 | heterogeneous crystallization interfacial electrontransfer Mn(II) oxidation manganese (oxyhydr)oxide iron (oxyhydr)oxide |
| ISSN号 | 0013-936X |
| DOI | 10.1021/acs.est.4c10093 |
| 英文摘要 | Heterogeneous crystallization of manganese (oxyhydr)oxides (MnO x ) on iron (oxyhydr)oxides (FeO x ) is crucial for the biogeochemical cycling of Mn, yet atomic-level insights into this process are important but relatively limited. Herein, we revealed the distinct adsorption, oxidation, and crystallization mechanisms of Mn on hematite (Hem), ferrihydrite (Fhy), and goethite (Gth). Gth exhibited highest ability in Mn(II) removal and oxidation, followed by Hem and Fhy. Manganite and hausmannite were the main MnO x products with distinct proportions, and morphologies cross the systems. MnO x growth mechanisms involve surface-induced nucleation, crystallization by particle attachment (CPA), and self-catalyzed growth. On Fhy, self-catalyzed growth was dominant; for Gth, surface-induced nucleation was prevalent, supplemented by CPA; and Hem combined all three mechanisms. These distinct mechanisms led to nanoparticles primarily of hausmannite on Gth and nanowires of manganite and hausmannite on Hem and Fhy, with those on Hem displaying lower aspect ratios. Differences in MnO x structure and morphology were attributed to Mn(II)-FeO x complexation, FeO x electronic band structure, and crystal structure mismatch between MnO x and FeO x , which respectively influenced the direct and indirect electron transfer and heterogeneous nucleation efficiency. This work advances our understanding of MnO x crystallization on FeO x at the nanoscale, explaining the diverse morphology and structure of MnO x in different environments. |
| WOS研究方向 | Engineering ; Environmental Sciences & Ecology |
| 语种 | 英语 |
| WOS记录号 | WOS:001427035300001 |
| 源URL | [http://ir.gig.ac.cn/handle/344008/82693]  |
| 专题 | 环境室 |
| 通讯作者 | Zhu, Runliang; Hochella Jr, Michael F.; Liu, Jing |
| 作者单位 | 1.Virginia Tech, Dept Geosci, Blacksburg, VA 24061 USA 2.Pacific Northwest Natl Lab, Energy & Environm Directorate, Richland, WA 99354 USA 3.Hunan Agr Univ, Coll Environm & Ecol, Changsha 410128, Peoples R China 4.Southern Marine Sci & Engn Guangdong Lab Guangzhou, Guangzhou 511458, Peoples R China 5.Chinese Acad Sci, Guangzhou Inst Geochem, Guangdong Prov Key Lab Mineral Phys & Mat, Guangzhou 510640, Peoples R China 6.Chinese Acad Sci, Guangzhou Inst Geochem, State Key Lab Adv Environm Technol, Guangzhou 510640, Peoples R China 7.Macau Univ Sci & Technol, Macau Environm Res Inst, Fac Innovat Engn, Taipa 999078, Macau, Peoples R China 8.CNSA Macau Ctr Space Explorat & Sci, Taipa 999078, Macau, Peoples R China 9.Macau Univ Sci & Technol, State Key Lab Lunar & Planetary Sci, Taipa 999078, Macau, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tong, Shouhao,Wei, Hongyan,Zhou, Junming,et al. Atomic Insights into the Heterogeneous Crystallization of Manganese (Oxyhydr)oxides on Typical Iron (Oxyhydr)oxides: from Adsorption to Oxidation to Crystallization[J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY,2025,59(8):3961-3971. |
| APA | Tong, Shouhao.,Wei, Hongyan.,Zhou, Junming.,Yang, Yixuan.,Zhu, Runliang.,...&Liu, Jing.(2025).Atomic Insights into the Heterogeneous Crystallization of Manganese (Oxyhydr)oxides on Typical Iron (Oxyhydr)oxides: from Adsorption to Oxidation to Crystallization.ENVIRONMENTAL SCIENCE & TECHNOLOGY,59(8),3961-3971. |
| MLA | Tong, Shouhao,et al."Atomic Insights into the Heterogeneous Crystallization of Manganese (Oxyhydr)oxides on Typical Iron (Oxyhydr)oxides: from Adsorption to Oxidation to Crystallization".ENVIRONMENTAL SCIENCE & TECHNOLOGY 59.8(2025):3961-3971. |
入库方式： OAI收割
来源：广州地球化学研究所
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