中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
首页 机构 成果 学者
  
  1. CAS IR Grid
  2. 力学研究所
  3. 中国科学院力学研究所
  4. 非线性力学国家重点实验室
Expanding the Electrochemical Stability Window: Unraveling the Role of Solvent Polarity and a WiSE-Compatible Strategy

文献类型：期刊论文

作者Lai GB(赖国彬); Lin JG(林金国); Mo WX(莫伟兴); Li XZ(李心竹); Jin, Xuting; Wu, Mingmao; Liu F(刘峰)
刊名JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
出版日期2025-04-05
卷号147期号:15页码:13071-13081
ISSN号0002-7863
DOI10.1021/jacs.5c04782
通讯作者Jin, Xuting(xutingjin@zzu.edu.cn) ; Wu, Mingmao(wumm20@fzu.edu.cn) ; Liu, Feng(liufeng@imech.ac.cn)
英文摘要Expanding the electrochemical stability window (ESW) of aqueous batteries significantly enhances their safety and energy density, addressing performance limitations and elevating their position in energy storage systems. Over the past decade, water-in-salt electrolyte (WiSE) has led to groundbreaking advancement in this field. However, a pressing question arises: can we further broaden the ESW through novel approaches? This study delves into this question, leveraging atomistic simulation along with ESW estimation and WiSE continuum theory to uncover that interfacial solvent polarity, subtly modulated by adding minor organic solvents, expands the ESW as well as promotes ion intercalation and transport. The strategy of incorporating minor organic solvents is compatible with WiSE, which not only advances our comprehension but also forges new research paths for post-WiSE era aqueous battery innovation. More importantly, our study provides a systematic way for theoretically estimating ESW and analyzing its enhancement mechanism in aqueous batteries.
分类号一类
WOS关键词IN-SALT ELECTROLYTE ; LITHIUM-ION ; AQUEOUS-ELECTROLYTE ; SUPERCONCENTRATED ELECTROLYTES ; GRAPHITE/ELECTROLYTE INTERFACE ; CATIONIC TRANSPORT ; SOLVATION SHEATH ; WATER ; GRAPHITE ; SAFE
资助项目Fujian Science and Technology Innovation Laboratory for Optoelectronic Information of China[11972349] ; Fujian Science and Technology Innovation Laboratory for Optoelectronic Information of China[22105040] ; Fujian Science and Technology Innovation Laboratory for Optoelectronic Information of China[22479130] ; Fujian Science and Technology Innovation Laboratory for Optoelectronic Information of China[22109009] ; National Natural Science Foundation of China[XDB0620101] ; Strategic Priority Research Program of the Chinese Academy of Sciences[2021ZZ127] ; Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China[2021J01588] ; Natural Science Foundation of Fujian Province of China
WOS研究方向Chemistry
语种英语
WOS记录号WOS:001460224000001
资助机构Fujian Science and Technology Innovation Laboratory for Optoelectronic Information of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China ; Natural Science Foundation of Fujian Province of China
其他责任者Jin, Xuting ; Wu, Mingmao ; 刘峰
源URL[http://dspace.imech.ac.cn/handle/311007/100801]  
专题力学研究所_非线性力学国家重点实验室
推荐引用方式
GB/T 7714		 Lai GB,Lin JG,Mo WX,et al. Expanding the Electrochemical Stability Window: Unraveling the Role of Solvent Polarity and a WiSE-Compatible Strategy[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2025,147(15):13071-13081.
APA 赖国彬.,林金国.,莫伟兴.,李心竹.,Jin, Xuting.,...&刘峰.(2025).Expanding the Electrochemical Stability Window: Unraveling the Role of Solvent Polarity and a WiSE-Compatible Strategy.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,147(15),13071-13081.
MLA 赖国彬,et al."Expanding the Electrochemical Stability Window: Unraveling the Role of Solvent Polarity and a WiSE-Compatible Strategy".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 147.15(2025):13071-13081.

入库方式： OAI收割

来源：力学研究所

浏览0
下载0
收藏0
其他版本

除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。