SERS Detection of Hydrophobic Molecules: Thio-β-Cyclodextrin-Driven Rapid Self-Assembly of Uniform Silver Nanoparticle Monolayers and Analyte Trapping
文献类型：期刊论文
| 作者 | Yuan, Qi1,2; Wang, Yunqing1 |
| 刊名 | BIOSENSORS-BASEL
 |
| 出版日期 | 2025 |
| 卷号 | 15期号:1页码:11 |
| 关键词 | silver nanoparticle beta-CD-SH self-assembly film SERS hydrophobic analyte |
| DOI | 10.3390/bios15010052 |
| 通讯作者 | Wang, Yunqing(yqwang@yic.ac.cn) |
| 英文摘要 | High-sensitivity and repeatable detection of hydrophobic molecules through the surface-enhanced Raman scattering (SERS) technique is a tough challenge because of their weak adsorption and non-uniform distribution on SERS substrates. In this research, we present a simple self-assembly protocol for monolayer SERS mediated by 6-deoxy-6-thio-beta-cyclodextrin (beta-CD-SH). This protocol allows for the rapid assembly of a compact silver nanoparticle (Ag NP) monolayer at the oil/water interface within 40 s, while entrapping analyte molecules within hotspots. The proposed method shows general applicability for detecting hydrophobic molecules, exemplified as Nile blue, Nile red, fluconazole, carbendazim, benz[a]anthracene, and bisphenol A. The detection limits range from 10-6to 10-9 M, and the relative standard deviations (RSDs) of signal intensity are less than 10%. Moreover, this method was used to investigate the release behaviors of a hydrophobic pollutant (Nile blue) adsorbed on the nanoplastic surface in the water environment. The results suggest that elevated temperatures, increased salinities, and the coexistence of fulvic acid promote the release of Nile blue. This simple and fast protocol overcomes the difficulties related to hotspot accessibility and detection repeatability for hydrophobic analytes, holding out extensive application prospects in environmental monitoring and chemical analysis. |
| WOS关键词 | SURFACE-ENHANCED RAMAN ; ADSORPTION ; TARGET ; DYES ; AU |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Instruments & Instrumentation |
| 语种 | 英语 |
| WOS记录号 | WOS:001404614300001 |
| 资助机构 | National Natural Science Foundation of China ; Taishan Scholar Project Special Funding ; Special Fund for Leading Scholar Program of Yantai |
| 源URL | [http://ir.yic.ac.cn/handle/133337/40454]  |
| 专题 | 烟台海岸带研究所_中科院海岸带环境过程与生态修复重点实验室 烟台海岸带研究所_山东省海岸带环境工程技术研究中心 |
| 通讯作者 | Wang, Yunqing |
| 作者单位 | 1.Chinese Acad Sci, Yantai Inst Coastal Zone Res, CAS Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yuan, Qi,Wang, Yunqing. SERS Detection of Hydrophobic Molecules: Thio-β-Cyclodextrin-Driven Rapid Self-Assembly of Uniform Silver Nanoparticle Monolayers and Analyte Trapping[J]. BIOSENSORS-BASEL,2025,15(1):11. |
| APA | Yuan, Qi,&Wang, Yunqing.(2025).SERS Detection of Hydrophobic Molecules: Thio-β-Cyclodextrin-Driven Rapid Self-Assembly of Uniform Silver Nanoparticle Monolayers and Analyte Trapping.BIOSENSORS-BASEL,15(1),11. |
| MLA | Yuan, Qi,et al."SERS Detection of Hydrophobic Molecules: Thio-β-Cyclodextrin-Driven Rapid Self-Assembly of Uniform Silver Nanoparticle Monolayers and Analyte Trapping".BIOSENSORS-BASEL 15.1(2025):11. |
入库方式： OAI收割
来源：烟台海岸带研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。