One-step electrodeposition of gold nanospheres/reduced graphene oxide for adsorptive stripping voltammetric determination of iron in seawater
文献类型:期刊论文
作者 | Ma, Cuncun1; Li, Ying2; Han, Haitao3 |
刊名 | MICROCHEMICAL JOURNAL
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出版日期 | 2025-05-01 |
卷号 | 212页码:7 |
关键词 | One-step electrodeposition Gold nanospheres Electrochemically reduced graphene oxide Iron Seawater |
ISSN号 | 0026-265X |
DOI | 10.1016/j.microc.2025.113499 |
通讯作者 | Li, Ying(liying68@sdtbu.edu.cn) ; Han, Haitao(hthan@yic.ac.cn) |
英文摘要 | An effective voltammetric method for determination of iron (Fe) in seawater was proposed based on the gold nanospheres (AuNSs)/electrochemically reduced graphene oxide (E-rGO) modified glassy carbon electrode (GCE). The AuNSs/E-rGO/GCE was prepared through a simple one-step electrodeposition method. E-rGO provides perfect conductivity, larger electrode surface, and more active sites for AuNSs which possess the ability to accelerate electron transfer and excellent electro-catalytic performance for the voltammetric determination of Fe3+. Benefiting from the synergistic effects of E-rGO and AuNSs, the AuNSs/E-rGO/GCE exhibited excellent performance for the voltammetric determination of Fe3+. Adsorptive stripping voltammetry was adopted for Fe3+ determination using the fabricated AuNSs/E-rGO/GCE with 1-(2-Pyridylazo)-2-naphthol as the complexing ligand. Under the optimal conditions, the AuNSs/E-rGO/GCE showed a limit of detection was 1.5 nM and linear range was 5 similar to 450 nM for Fe3+ determination. In addition, the AuNSs/E-rGO/GCE has been successfully applied to determine the total dissolved Fe in real seawater samples. |
WOS关键词 | GLASSY-CARBON ELECTRODE ; TRACE-METALS ; PHYTOPLANKTON ; WATERS ; SENSOR ; QUANTIFICATION ; NANOCOMPOSITES ; LIMITATION ; REDUCTION ; ACID |
WOS研究方向 | Chemistry |
语种 | 英语 |
WOS记录号 | WOS:001459100800001 |
资助机构 | National Natural Science Foundation of China |
源URL | [http://ir.yic.ac.cn/handle/133337/40474] ![]() |
专题 | 烟台海岸带研究所_中科院海岸带环境过程与生态修复重点实验室 烟台海岸带研究所_山东省海岸带环境工程技术研究中心 |
通讯作者 | Li, Ying; Han, Haitao |
作者单位 | 1.Shandong Technol & Business Univ, Law Sch, Yantai 264003, Peoples R China 2.Shandong Technol & Business Univ, Sch Informat & Elect Engn, Yantai 264003, Peoples R China 3.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Res Ctr Coastal Environm Engn Technol Shandong Pro, Shandong Key Lab Coastal Environm Proc,CAS Key Lab, Yantai 264003, Peoples R China |
推荐引用方式 GB/T 7714 | Ma, Cuncun,Li, Ying,Han, Haitao. One-step electrodeposition of gold nanospheres/reduced graphene oxide for adsorptive stripping voltammetric determination of iron in seawater[J]. MICROCHEMICAL JOURNAL,2025,212:7. |
APA | Ma, Cuncun,Li, Ying,&Han, Haitao.(2025).One-step electrodeposition of gold nanospheres/reduced graphene oxide for adsorptive stripping voltammetric determination of iron in seawater.MICROCHEMICAL JOURNAL,212,7. |
MLA | Ma, Cuncun,et al."One-step electrodeposition of gold nanospheres/reduced graphene oxide for adsorptive stripping voltammetric determination of iron in seawater".MICROCHEMICAL JOURNAL 212(2025):7. |
入库方式: OAI收割
来源:烟台海岸带研究所
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