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Recent Advances in the Formation and Transformation of Propargyl Radical

文献类型：期刊论文

作者Xiao, Bi-Yin2,3; Huang, Wei1,2,3; Zhang, Feng-Hua2,3
刊名EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
出版日期2025-04-22
页码40
关键词allenyl compound allenyl radical asymmetric catalytic radical transformation propargyl compound propargyl radical
ISSN号1434-193X
DOI10.1002/ejoc.202500302
英文摘要Propargyl radical is a very important free radical in organic synthesis. The tautomerization with the allenyl radical enables the diverse reactivities, and then, propargyl compounds and allenes can be obtained. Because of its properties, how to control the chemical selectivity and enantioselectivity is the key in the radical propargyl functionalization. In this review, the reactions involving propargyl radicals in recent years are summarized according to the means for the production of propargyl radicals, different reaction types, and asymmetric catalytic transformations.
WOS关键词1,3-ENYNES ; ENANTIOCONVERGENT ; ACCESS ; 1,4-ALKYLARYLATION ; PHOTOREDOX
资助项目National Natural Science Foundation of China ; National Key Research and Development Program of China[2023YFD1800100] ; Hangzhou Institute for Advanced Study, UCAS[2023HIAS-V006] ; Hangzhou Institute for Advanced Study, UCAS[2024HIAS-V008] ; [22401060]
WOS研究方向Chemistry
语种英语
WOS记录号WOS:001471864500001
出版者WILEY-V C H VERLAG GMBH
源URL[http://119.78.100.183/handle/2S10ELR8/317497]  
专题新药研究国家重点实验室
通讯作者Zhang, Feng-Hua
作者单位1.Chinese Acad Sci, Shanghai Inst Mat Med, State Key Lab Drug Res, Shanghai 201203, Peoples R China
2.Univ Chinese Acad Sci, Beijing 101408, Peoples R China
3.Univ Chinese Acad Sci, Hangzhou Inst Adv Study, Sch Pharmaceut Sci & Technol, Hangzhou 310024, Peoples R China
推荐引用方式
GB/T 7714		 Xiao, Bi-Yin,Huang, Wei,Zhang, Feng-Hua. Recent Advances in the Formation and Transformation of Propargyl Radical[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,2025:40.
APA Xiao, Bi-Yin,Huang, Wei,&Zhang, Feng-Hua.(2025).Recent Advances in the Formation and Transformation of Propargyl Radical.EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,40.
MLA Xiao, Bi-Yin,et al."Recent Advances in the Formation and Transformation of Propargyl Radical".EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2025):40.

入库方式： OAI收割

来源：上海药物研究所

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