Thickness determination of molecularly thin lubricant films by angle-dependent X-ray photoelectron spectroscopy
文献类型:期刊论文
作者 | Pang ZJ(庞重军) ; Bai MW(白明武) |
刊名 | Applied Surface Science
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出版日期 | 2007 |
卷号 | 253页码:4688-4693 |
关键词 | Thickness determination Metrology Angle-dependent XPS Lubricant Perfluoropolyether |
ISSN号 | 0169-4332 |
通讯作者 | 白明武 |
中文摘要 | An angle-dependent X-ray photoelectron spectroscopy (XPS) method used to measure the thickness of molecularly thin lubricants was developed. The method was built based on an island model of patched overlayer on a flat substrate by using the photoemission signal solely from the lubricant film. Typical molecularly thin Zdol films on the CHx overcoat of unused commercial magnetic disks were measured to verify the metrology. The lubricant thickness determined by the metrology was equal to the recent result by thermostatic high vacuum atomic force microscopy. The measured deduction in the thickness of the molecularly thin lubricant films, successively irradiated by the monochromatic source operated at 14 kV/250 W, was as low as 1 Ǻ during the first irradiation hour. XPS spectra showed that no hydrocarbons, water or oxygen were adsorbed over the Zdol outer surfaces in the tested XPS conditions. The inelastic mean free path (IMFP) of C 1s in Zdol or in CHx was found to be independent of take off angle (TOA) when TOA < 408. The IMFP of C 1s in Zdol was 63.5 Ǻ and the lubricant island thickness was 35 Ǻ. |
学科主题 | 材料科学与物理化学 |
收录类别 | SCI |
资助信息 | Innovative Group Foundation from National Science Foundation of China (50421502);National Natural Science Foundation of China (50675217);National 973 Program (2007CB607601);“100 Talents” Program of Chinese Academy of Sciences |
语种 | 英语 |
WOS记录号 | WOS:000244977000038 |
公开日期 | 2013-11-01 |
源URL | [http://210.77.64.217/handle/362003/4105] ![]() |
专题 | 兰州化学物理研究所_固体润滑国家重点实验室 |
推荐引用方式 GB/T 7714 | Pang ZJ,Bai MW. Thickness determination of molecularly thin lubricant films by angle-dependent X-ray photoelectron spectroscopy[J]. Applied Surface Science,2007,253:4688-4693. |
APA | 庞重军,&白明武.(2007).Thickness determination of molecularly thin lubricant films by angle-dependent X-ray photoelectron spectroscopy.Applied Surface Science,253,4688-4693. |
MLA | 庞重军,et al."Thickness determination of molecularly thin lubricant films by angle-dependent X-ray photoelectron spectroscopy".Applied Surface Science 253(2007):4688-4693. |
入库方式: OAI收割
来源:兰州化学物理研究所
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