中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
An NMR-Based Procedure for Evaluating the Apparent Surface Relaxivity and Pore Size Distribution of Soils

文献类型:期刊论文

作者Tian, Huihui1; Wu, Guangshui2; Wei, Changfu1
刊名GEOTECHNICAL TESTING JOURNAL
出版日期2023-12-06
页码16
关键词nuclear magnetic resonance relaxometry water proton relaxation surface relaxivity pore size distribution
ISSN号0149-6115
DOI10.1520/GTJ20230395
英文摘要A nuclear magnetic resonance-based procedure is proposed to evaluate the surface relaxivity parameters pk (k = 1 or 2 for spin-lattice or spin-spin relaxation) and pore size distributions (PSDs) of six different soils, including four expansive clays, a silt, and a loess. It is shown that both p1 and p2 first increases with specific water content (w) until w increases up to about 10 %, and then p1 approaches a stable value, whereas p2 slightly decreases. The underlying mechanisms for the surface relaxation of water protons are evaluated. It is shown that the water proton relaxation in expansive clays is controlled by the partially fixed ions confined in diffuse double layers, whereas that in silt and loess is dictated by the proton exchange between water molecules and surface hydroxyls and the dipole-dipole interaction between water molecules and hydrogen-bonding molecules. As a consequence, the pk values of silt and loess are larger than those of expansive clays. A new method is proposed to determine the apparent surface relaxivity parameter that is used to determine the PSD of soil based on the surface relaxation time distribution. The proposed procedure is validated by comparing the estimated PSDs with the measurements of mercury intrusion porosimetry.
资助项目National Natural Science Foundation of China (NSFC)[42072312] ; Department of Science and Technology of Guangxi[AD20325010] ; NSFC[51939011]
WOS研究方向Engineering ; Geology
语种英语
WOS记录号WOS:001115864700001
出版者AMER SOC TESTING MATERIALS
源URL[http://119.78.100.198/handle/2S6PX9GI/40104]  
专题中科院武汉岩土力学所
通讯作者Wei, Changfu
作者单位1.Chinese Acad Sci, Inst Rock & Soil Mech, State Key Lab Geomech & Geotech Engn, 2 Xiaohongshan, Wuhan 430071, Hubei, Peoples R China
2.Guilin Univ Technol, Guangxi Key Lab Geomech & Geotech Engn, 12 Jiangan Rd, Guilin 541004, Peoples R China
推荐引用方式
GB/T 7714
Tian, Huihui,Wu, Guangshui,Wei, Changfu. An NMR-Based Procedure for Evaluating the Apparent Surface Relaxivity and Pore Size Distribution of Soils[J]. GEOTECHNICAL TESTING JOURNAL,2023:16.
APA Tian, Huihui,Wu, Guangshui,&Wei, Changfu.(2023).An NMR-Based Procedure for Evaluating the Apparent Surface Relaxivity and Pore Size Distribution of Soils.GEOTECHNICAL TESTING JOURNAL,16.
MLA Tian, Huihui,et al."An NMR-Based Procedure for Evaluating the Apparent Surface Relaxivity and Pore Size Distribution of Soils".GEOTECHNICAL TESTING JOURNAL (2023):16.

入库方式: OAI收割

来源:武汉岩土力学研究所

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