The extraction of carbonate components from soils and sediments: an experimental investigation by using different leaching acids
文献类型:期刊论文
作者 | Xu, Yifu3,5,6; Li, Yuanchuan1,2,4; Wang, Ping3,5,6; Li, Jiangshan3,5,6 |
刊名 | JOURNAL OF SOILS AND SEDIMENTS
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出版日期 | 2024-05-14 |
页码 | 9 |
关键词 | Carbonate extraction Soils Sediments Exchangeable components Silicate components |
ISSN号 | 1439-0108 |
DOI | 10.1007/s11368-024-03779-w |
英文摘要 | PurposeCarbonate components in soils and sediments play a crucial role in the study of surface processes and the reconstruction of paleoclimates. The extraction of carbonate components from soils and sediments is often carried out using different types of acids. However, which reagents can effectively extract the carbonate components while minimizing the destruction of non-carbonate minerals in soils and sediments has not been fully explored yet.MethodsThe present study conducted a series of conditional leaching experiments on six standard soil and sediment samples with diverse geological backgrounds and varying carbonate contents.ResultsThe results revealed that dilute acetic acid (HOAc, 0.5 mol/L) performed better than acid solution (HCl) and acetic acid buffer solution (NaOAc-HOAc) in promoting the complete dissolution of carbonate minerals and avoiding the dissolution of clay minerals. It was also observed that pre-treating the samples with neutral ammonium acetate buffer solution (NH4OAc) or potassium chloride buffer solution (KCl) was necessary to remove exchangeable components. The Mg/Ca ratios of the silicate components after leaching carbonate in the standard soil and sediment samples we used exhibited significant differences (ranging from 0.41 to 1.60).ConclusionThe dilute acetic acid (HOAc, 0.5 mol/L) is advisable for the extraction of carbonate components from soils and sediments, and the pre-treatment of removing exchangeable components is essential for samples with low carbonate content. It is more reasonable to use the element ratios of the dilute acid insoluble fraction or the average compositions of minerals in soils and sediments for individual correction for the contribution of the silicate components. |
资助项目 | the National Key Research and Development Program of China[2022YFC3901205] ; National Key Research and Development Program of China |
WOS研究方向 | Environmental Sciences & Ecology ; Agriculture |
语种 | 英语 |
WOS记录号 | WOS:001222379000001 |
出版者 | SPRINGER HEIDELBERG |
源URL | [http://119.78.100.198/handle/2S6PX9GI/41317] ![]() |
专题 | 中科院武汉岩土力学所 |
通讯作者 | Li, Jiangshan |
作者单位 | 1.Chinese Acad Sci, Key Lab Cenozo Geol & Environm, Inst Geol & Geophys, Beijing 100029, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.IRSM CAS HK PolyU Joint Lab Solid Waste Sci, Wuhan 430071, Peoples R China 4.Chinese Acad Sci, Innovat Acad Earth Sci, Beijing 100029, Peoples R China 5.Chinese Acad Sci, Inst Rock & Soil Mech, State Key Lab Geomech & Geotech Engn, Wuhan 430071, Peoples R China 6.Hubei Prov Key Lab Contaminated Sludge & Soil Sci, Wuhan 430071, Peoples R China |
推荐引用方式 GB/T 7714 | Xu, Yifu,Li, Yuanchuan,Wang, Ping,et al. The extraction of carbonate components from soils and sediments: an experimental investigation by using different leaching acids[J]. JOURNAL OF SOILS AND SEDIMENTS,2024:9. |
APA | Xu, Yifu,Li, Yuanchuan,Wang, Ping,&Li, Jiangshan.(2024).The extraction of carbonate components from soils and sediments: an experimental investigation by using different leaching acids.JOURNAL OF SOILS AND SEDIMENTS,9. |
MLA | Xu, Yifu,et al."The extraction of carbonate components from soils and sediments: an experimental investigation by using different leaching acids".JOURNAL OF SOILS AND SEDIMENTS (2024):9. |
入库方式: OAI收割
来源:武汉岩土力学研究所
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