Nanoparticles via Crystallization: A Chemical Reaction Control Study of Copper Oxides
文献类型：期刊论文
| 作者 | Chen KF ; Xue DF |
| 刊名 | nanoscience and nanotechnology letters
 |
| 出版日期 | 2012 |
| 卷号 | 4期号:1页码:1-12 |
| 关键词 | LI-ION BATTERIES CUPROUS-OXIDE HOLLOW ARCHITECTURES PHASE-TRANSFORMATION BRANCHING GROWTH TEMPLATE ROUTE IN-SITU NANOCRYSTALS CU2O SUPERSTRUCTURES |
| ISSN号 | 1941-4900 |
| 通讯作者 | xue df |
| 中文摘要 | nanoscale crystallization is vital for synthesis of morphology- and size-controlled nanocrystals, however, the role of chemical reactions during crystallization is less thoroughly studied. from a kinetic viewpoint, this review article presents a systematical study of the effect of chemical reactions on the hydrothermal crystallization of copper oxides. the summarized results show that the chemical reaction can be adjusted by various kinetic factors such as concentration, temperature, and ph, which can effectively control particle size and shape. both reaction rate and growth rate of copper oxides nanocrystals were increased with increasing temperature and ph, while low and medium cu2+ concentrations can maintain appropriate chemical reaction rate and shape control. with weak hydrolysis limit water can have little influence on reaction kinetics, while oh- increases reaction kinetics and facilitates the formation of shape-controlled copper oxides nanocrystals. the triple role of citrate was identified, ligands, reducing agents, and weak bases, which are related to different chemical reactions. the crystallization habits of nanoparticles synthesized in different chemical reaction routes were also discussed. |
| 收录类别 | SCI收录期刊论文 |
| 语种 | 英语 |
| WOS记录号 | WOS:000303220600001 |
| 公开日期 | 2013-11-02 |
| 源URL | [http://ir.ciac.jl.cn/handle/322003/49028]  |
| 专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
| 推荐引用方式 GB/T 7714 | Chen KF,Xue DF. Nanoparticles via Crystallization: A Chemical Reaction Control Study of Copper Oxides[J]. nanoscience and nanotechnology letters,2012,4(1):1-12. |
| APA | Chen KF,&Xue DF.(2012).Nanoparticles via Crystallization: A Chemical Reaction Control Study of Copper Oxides.nanoscience and nanotechnology letters,4(1),1-12. |
| MLA | Chen KF,et al."Nanoparticles via Crystallization: A Chemical Reaction Control Study of Copper Oxides".nanoscience and nanotechnology letters 4.1(2012):1-12. |
入库方式： OAI收割
来源：长春应用化学研究所
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