Enhanced activity of molybdovanadophosphoric acid modified Pt electrode for the electrooxidation of methanol
文献类型:期刊论文
作者 | Feng LG ; Lv Q ; Sun XJ ; Yao SK ; Liu CP ; Xing W |
刊名 | journal of electroanalytical chemistry
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出版日期 | 2012 |
卷号 | 664页码:14-19 |
关键词 | PEM FUEL-CELLS PT/C ELECTROCATALYSTS CARBON NANOTUBES OXIDATION PLATINUM CATALYSTS CO NANOPARTICLES POLYCRYSTALLINE VOLTAMMETRY |
ISSN号 | 1572-6657 |
通讯作者 | xing w |
中文摘要 | the keggin-structure molybdovanadophosphoric acid (h3+xpmo12-xvxo40, x = 1, 2, 3, denoted as pmv) modified pt electrode was studied by electrochemical measurements for methanol oxidation. it was discovered that both the catalytic activity and stability of the pmv modified pt electrode were significantly enhanced. with the increase of the vanadium content in pmv, the catalytic activity and stability for methanol electrooxidation were also increased. the enhancements were attributed to the special properties of pmv, which increased the electron transfer coefficient of the rate-determining step. therefore, the pmv has potential application as promoter for methanol electrooxidation in direct methanol fuel cell. (c) 2011 elsevier b.v. all rights reserved. |
收录类别 | SCI收录期刊论文 |
语种 | 英语 |
WOS记录号 | WOS:000300816100003 |
公开日期 | 2013-11-02 |
源URL | [http://ir.ciac.jl.cn/handle/322003/49033] ![]() |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Feng LG,Lv Q,Sun XJ,et al. Enhanced activity of molybdovanadophosphoric acid modified Pt electrode for the electrooxidation of methanol[J]. journal of electroanalytical chemistry,2012,664:14-19. |
APA | Feng LG,Lv Q,Sun XJ,Yao SK,Liu CP,&Xing W.(2012).Enhanced activity of molybdovanadophosphoric acid modified Pt electrode for the electrooxidation of methanol.journal of electroanalytical chemistry,664,14-19. |
MLA | Feng LG,et al."Enhanced activity of molybdovanadophosphoric acid modified Pt electrode for the electrooxidation of methanol".journal of electroanalytical chemistry 664(2012):14-19. |
入库方式: OAI收割
来源:长春应用化学研究所
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