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Ultra-Dilute high-entropy alloy catalyst with core-shell structure for high-active hydrogenation of furfural to furfuryl alcohol at mild temperature

文献类型：期刊论文

作者Tu, Ren3; Liang, Kaili3; Sun, Yan3; Wu, Yangwen4; Lv, Wei1; Jia, Charles Q.5; Jiang, Enchen3; Wu, Yujian3; Fan, Xudong3; Zhang, Bing4
刊名CHEMICAL ENGINEERING JOURNAL
出版日期2023-01-15
卷号452页码:11
关键词Furfural High-entropy alloy Ultra-dilute alloy Hydrogenation Core-shell structure
ISSN号1385-8947
DOI10.1016/j.cej.2022.139526
通讯作者Lu, Qiang(qianglu@mail.ustc.edu.cn) ; Zhang, Bingsen(bszhang@imr.ac.cn) ; Xu, Xiwei(xuxiwei200801@hotmail.com)
英文摘要Furfuryl Alcohol (FOL) from the catalytic hydrogenation of furfural represented a promising intermediate for industrial application. However, the high selectively of FOL in mild temperature was limited due to the over hydrogenation. Here, we synthesized the novel ultra-dilute high-entropy alloys (HEAs) with multiple metal sites and core-shell structure for boosting the selectivity of furfural hydrogenation to furfuryl alcohol. The results showed that the furfural was converted to FOL with the conversion of 87.32% and selectivity of 100% at 90 degrees C over ultra-dilute HEA (NiCoCuZnFe/C-800). The catalyst had redistribution of electrons between Cu (2.00) and atomically dispersed Zn (1.65) due to the different electronegativity. The electron-rich Cu repelled the furan ring and prevented the over hydrogenation, while the atomically dispersed Zn presented the strongest -CHO adsorption performance. Moreover, the core-shell structure enhanced the stability of the catalysts during hy-drogenation reaction and the porous carbon shell improved the transferring of furfural and electronic.
WOS关键词TOTAL-ENERGY CALCULATIONS ; SOLID-SOLUTION PHASE ; SELECTIVE HYDROGENATION ; LOCALIZATION ; BIOMASS ; ADSORPTION ; STABILITY ; CHEMICALS ; ALDEHYDES ; SURFACES
资助项目Chinese National Natural Science Foundation ; Natural Science Foundation of Guangdong Province, China ; [52006074] ; [2021A1515010886]
WOS研究方向Engineering
语种英语
WOS记录号WOS:000871102700006
出版者ELSEVIER SCIENCE SA
资助机构Chinese National Natural Science Foundation ; Natural Science Foundation of Guangdong Province, China
源URL[http://ir.giec.ac.cn/handle/344007/37659]  
专题中国科学院广州能源研究所
通讯作者Lu, Qiang; Zhang, Bingsen; Xu, Xiwei
作者单位1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Beijing, Peoples R China
2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang, Peoples R China
3.South China Agr Univ, Coll Mat & Energy, Key Lab Biobased Mat & Energy, Minist Educ, Guangzhou 510640, Peoples R China
4.North China Elect Power Univ, Natl Engn Lab Biomass Power Generat Equipment, Beijing 102206, Peoples R China
5.Univ Toronto, Dept Chem Engn & Appl Chem, 200 Coll St, Toronto, ON M5S 3E5, Canada
推荐引用方式
GB/T 7714		 Tu, Ren,Liang, Kaili,Sun, Yan,et al. Ultra-Dilute high-entropy alloy catalyst with core-shell structure for high-active hydrogenation of furfural to furfuryl alcohol at mild temperature[J]. CHEMICAL ENGINEERING JOURNAL,2023,452:11.
APA Tu, Ren.,Liang, Kaili.,Sun, Yan.,Wu, Yangwen.,Lv, Wei.,...&Xu, Xiwei.(2023).Ultra-Dilute high-entropy alloy catalyst with core-shell structure for high-active hydrogenation of furfural to furfuryl alcohol at mild temperature.CHEMICAL ENGINEERING JOURNAL,452,11.
MLA Tu, Ren,et al."Ultra-Dilute high-entropy alloy catalyst with core-shell structure for high-active hydrogenation of furfural to furfuryl alcohol at mild temperature".CHEMICAL ENGINEERING JOURNAL 452(2023):11.

入库方式： OAI收割

来源：广州能源研究所

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