Exploration of LiCoO2-doped cobalt oxide composite for thermochemical energy storage at high temperature
文献类型：期刊论文
| 作者 | Wu, Rongjun1; Deng, Lisheng2; Huang, Hongyu2; Kubota, Mitsuhiro1; Kobayashi, Noriyuki1 |
| 刊名 | JOURNAL OF ENERGY STORAGE
 |
| 出版日期 | 2022-11-30 |
| 卷号 | 55页码:12 |
| 关键词 | Thermochemical energy storage Reduction oxidation process Cobalt oxide Lithium compound dopant Cyclic stability |
| ISSN号 | 2352-152X |
| DOI | 10.1016/j.est.2022.105774 |
| 通讯作者 | Kobayashi, Noriyuki(kobayashi.noriyuki@material.nagoya-u.ac.jp) |
| 英文摘要 | Due to the high energy storage density, long-term energy storage and long-distance transport possibility, as well as operation possibility under open system, metal oxide-based thermochemical energy storage (TCS) was considered as a promising candidate for efficient energy utilization. Herein, lithium cobalt oxide (LiCoO2)-doped cobalt oxide composite was proposed and investigated for the metal oxide-based TCS application. Doping with LiCoO2 diminished the onset temperature of reduction and re-oxidation by 50 degrees C and 65 degrees C, respectively. Also, doping with appropriate amount of LiCoO2 contributed to improve the re-oxidation rate of cobalt oxide-based system under a high cooling rate, resulting the discharging heat (423.8 kJ/kg) increased significantly in com-parison with pure cobalt oxide (289.8 kJ/kg) under temperature cooling rate of 20 degrees C/min. It was found that doping with LiCoO2 decreased the apparent activation energy of reduction and oxidation. Meanwhile, the results obtained from in-situ X-ray diffraction indicate that LiCoO2 was involved in the reduction/re-oxidation process. Moreover, excellent repeatability of the composite was attested in 30 cycles. Hence, doping with LiCoO2 was verified as an effective method to expanding the possibility of cobalt oxide for TCS application. |
| WOS关键词 | MN2O3/MN3O4 REDOX COUPLE ; LINO3-DOPED MG(OH)(2) ; MAGNESIUM-HYDROXIDE ; PEROVSKITE OXIDES ; MANGANESE OXIDES ; SYSTEMS ; CYCLES ; CO ; MN ; FE |
| 资助项目 | Knowledge Hub Aichi ; Aichi Prefectural Government, Japan ; National Natural Science Foundation of China[52176091] |
| WOS研究方向 | Energy & Fuels |
| 语种 | 英语 |
| WOS记录号 | WOS:000873784400001 |
| 出版者 | ELSEVIER |
| 资助机构 | Knowledge Hub Aichi ; Aichi Prefectural Government, Japan ; National Natural Science Foundation of China |
| 源URL | [http://ir.giec.ac.cn/handle/344007/37695]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Kobayashi, Noriyuki |
| 作者单位 | 1.Nagoya Univ, Grad Sch Engn, Dept Chem Syst Engn, Chikusa Ku, Furo Cho, Nagoya, Aichi 4648603, Japan 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, 2 Nengyuan Rd, Guangzhou 510640, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu, Rongjun,Deng, Lisheng,Huang, Hongyu,et al. Exploration of LiCoO2-doped cobalt oxide composite for thermochemical energy storage at high temperature[J]. JOURNAL OF ENERGY STORAGE,2022,55:12. |
| APA | Wu, Rongjun,Deng, Lisheng,Huang, Hongyu,Kubota, Mitsuhiro,&Kobayashi, Noriyuki.(2022).Exploration of LiCoO2-doped cobalt oxide composite for thermochemical energy storage at high temperature.JOURNAL OF ENERGY STORAGE,55,12. |
| MLA | Wu, Rongjun,et al."Exploration of LiCoO2-doped cobalt oxide composite for thermochemical energy storage at high temperature".JOURNAL OF ENERGY STORAGE 55(2022):12. |
入库方式： OAI收割
来源：广州能源研究所
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