Effect of air introduction on filamentous coke during CO2 reforming of tar with core-shell catalysts
文献类型：期刊论文
| 作者 | Tian, Yunlong1; Ma, Xiaoqian1; Chen, Xinfei2 |
| 刊名 | JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS
 |
| 出版日期 | 2022-11-01 |
| 卷号 | 168页码:11 |
| 关键词 | CO2 reforming tar Coke deposition Core-shell Ni8Co Air |
| ISSN号 | 0165-2370 |
| DOI | 10.1016/j.jaap.2022.105765 |
| 通讯作者 | Ma, Xiaoqian(epxqma@scut.edu.cn) |
| 英文摘要 | The coke accumulation is the main factor affecting the activity of nickel-based catalysts during the CO2 reforming of tar. In this work, toluene is chosen to study the influence of filamentous coke on the coke-forming mechanism of the Ni/La2O3 @SiO2 catalyst. Two methods are proposed to address the problem of reduced tar conversion of Ni/La2O3 @SiO2 due to coke deposition. The Ni/La2O3 @SiO2 is first modified with cobalt doping to improve the resistance to coke accumulation. The Ni8Co/La2O3 @SiO2 catalyst showed higher carbon conversion (50-75%) and hydrogen conversion (35-55%) than Ni/La2O3 @SiO2 within the 5 h tar reforming process. And the used Ni8Co/La2O3 @SiO2 catalysts had only 0.1 g/g of filamentous coke after reforming reaction. Next, air is intro-duced to oxidize the deposited coke to address the problem of coke accumulation affecting catalyst activity. An appropriate air flow rate could provide oxidation of the coke and prolong the reaction activity of the catalyst from 5 h to 10 h. |
| WOS关键词 | NI-BASED CATALYSTS ; NICKEL-CATALYSTS ; BIOMASS GASIFICATION ; PARTIAL OXIDATION ; STEAM ; METHANE ; TOLUENE ; PERFORMANCE ; HYDROGEN ; NANOPARTICLES |
| 资助项目 | Key Technologies Research and Development Program of China ; [2018YFC1901203] |
| WOS研究方向 | Chemistry ; Energy & Fuels ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000882399700003 |
| 出版者 | ELSEVIER |
| 资助机构 | Key Technologies Research and Development Program of China |
| 源URL | [http://ir.giec.ac.cn/handle/344007/37841]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Ma, Xiaoqian |
| 作者单位 | 1.South China Univ Technol, Sch Elect Power, Guangdong Prov Key Lab Efficient & Clean Energy Ut, Guangzhou 510640, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tian, Yunlong,Ma, Xiaoqian,Chen, Xinfei. Effect of air introduction on filamentous coke during CO2 reforming of tar with core-shell catalysts[J]. JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS,2022,168:11. |
| APA | Tian, Yunlong,Ma, Xiaoqian,&Chen, Xinfei.(2022).Effect of air introduction on filamentous coke during CO2 reforming of tar with core-shell catalysts.JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS,168,11. |
| MLA | Tian, Yunlong,et al."Effect of air introduction on filamentous coke during CO2 reforming of tar with core-shell catalysts".JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS 168(2022):11. |
入库方式： OAI收割
来源：广州能源研究所
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