A review on catalysts for electrocatalytic and photocatalytic reduction of N-2 to ammonia
文献类型：期刊论文
| 作者 | Lin, Shanshan2,3; Zhang, Xinghua1; Chen, Lungang1; Zhang, Qi1; Ma, Longlong1; Liu, Jianguo1 |
| 刊名 | GREEN CHEMISTRY
 |
| 出版日期 | 2022-11-04 |
| 页码 | 24 |
| ISSN号 | 1463-9262 |
| DOI | 10.1039/d2gc03174d |
| 通讯作者 | Liu, Jianguo(liujg@seu.edu.cn) |
| 英文摘要 | The ammonia (NH3) synthesis industry is significant for many aspects of human progress and the global economy, especially in the fields of fertilizers, hydrocarbon-free energy carriers, and the production of emerging clean fuels. The world's energy for ammonia synthesis accounts for roughly 1-2% of social energy consumption. As an environmentally friendly and cheap raw material, N-2 is abundant in nature. Therefore, the search for efficient catalysts that can convert N-2 to NH3 under mild conditions with low energy consumption has always been a hot research topic in the field of catalysis. The conversion and utilization of renewable energy sources such as light and electricity, especially chemical energy, is of great importance to human society in terms of energy saving and environmental protection. One of the ways to reduce N-2 to NH3 is the electrochemical nitrogen reduction reaction (e-NRR); however, the improvement of e-NRR activity is severely limited by the ultra-high chemical stability of N equivalent to N bonds and the competition from the hydrogen evolution reaction (HER). The three main types of catalysts, metallic (metal complex) and non-metallic catalysts, together with natural biocatalysts, have been the target of development and improvement by researchers as suitable catalysts. In terms of photocatalytic N-2 synthesis of ammonia, due to the relatively stable chemical properties of N-2 molecules, it is difficult for traditional photocatalytic materials to generate the activity of reducing N-2 molecules. Through continuous innovation and improvement of photocatalysts, researchers are able to increase the catalytic sites of catalysts and find suitable supporting materials to activate N-2 molecules, which greatly improves the efficiency of photocatalytic N-2 synthesis of ammonia. This review highlights the recent progress and development of photocatalysts and electrocatalysts for the synthesis of NH3 from N-2, and briefly introduces the advantages of various catalysts and the comparison of synthesis efficiency. It is expected to provide a reference for the development of new processes that can produce high value-added chemicals. |
| WOS关键词 | GRAPHITIC CARBON NITRIDE ; ELECTROCHEMICAL NITROGEN REDUCTION ; LARGE-SCALE PRODUCTION ; AMBIENT CONDITIONS ; OXYGEN VACANCIES ; (G-C3N4)-BASED PHOTOCATALYSTS ; PHOTOCHEMICAL-SYNTHESIS ; ATMOSPHERIC-PRESSURE ; VANADIUM NITROGENASE ; HYDROGEN GENERATION |
| 资助项目 | National Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities ; [51976225] ; [52236010] ; [2242022R10058] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics |
| 语种 | 英语 |
| WOS记录号 | WOS:000883001300001 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 资助机构 | National Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities |
| 源URL | [http://ir.giec.ac.cn/handle/344007/37859]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Liu, Jianguo |
| 作者单位 | 1.Southeast Univ, Sch Energy & Environm, Minist Educ, Key Lab Energy Thermal Convers & Control, Nanjing 210096, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lin, Shanshan,Zhang, Xinghua,Chen, Lungang,et al. A review on catalysts for electrocatalytic and photocatalytic reduction of N-2 to ammonia[J]. GREEN CHEMISTRY,2022:24. |
| APA | Lin, Shanshan,Zhang, Xinghua,Chen, Lungang,Zhang, Qi,Ma, Longlong,&Liu, Jianguo.(2022).A review on catalysts for electrocatalytic and photocatalytic reduction of N-2 to ammonia.GREEN CHEMISTRY,24. |
| MLA | Lin, Shanshan,et al."A review on catalysts for electrocatalytic and photocatalytic reduction of N-2 to ammonia".GREEN CHEMISTRY (2022):24. |
入库方式： OAI收割
来源：广州能源研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。