Ru-RuO2-Nb2O5/H beta zeolite catalyst for high-active hydrogenation of lignin derivatives at room temperature
文献类型：期刊论文
| 作者 | Tu, Ren1; Lv, Wei3; Sun, Yan1; Wu, Yujian1; Wu, Yangwen2; Fan, Xudong1; Jiang, Enchen1; Lu, Qiang2; Xu, Xiwei1 |
| 刊名 | CHEMICAL ENGINEERING JOURNAL
 |
| 出版日期 | 2023-02-01 |
| 卷号 | 453页码:14 |
| 关键词 | Phenol Interface catalyst Hydrogenation Cyclohexanol |
| ISSN号 | 1385-8947 |
| DOI | 10.1016/j.cej.2022.139718 |
| 通讯作者 | Xu, Xiwei(xuxiwei200801@hotmail.com) |
| 英文摘要 | Cyclohexanol is an important intermediate used in the synthesis of a variety of high value-added chemicals. In this work, a novel Ru-RuO2-Nb2O5/H beta catalyst was prepared and employed to directly hydrogenate phenol to cyclohexanol at room temperature. Moreover, the influence of Nb content and the reduction time on the activity of Ru-RuO2-Nb2O5/H beta was investigated for obtaining the catalytic mechanism as well as the structural char-acteristics of the catalyst. The results showed that the phenol was almost converted into cyclohexanol with a high yield of 98.2 % via 0.3 %Ru2%Nb-H beta-1 h catalyst at 30 degrees C and 2 MPaH2. The high hydrogenation activity at room temperature was attributed to the Ru-RuO2-Nb2O5 interface in catalyst via TEM, XPS, H2-TPR and NH3-TPD analysis. Moreover, the DFT calculation results showed that Nb2O5 inhibited the reduction of RuO2 species, resulting in the formation of Ru-RuO2-Nb2O5 interface and the adsorption of phenol on the Ru-RuO2 interface was stronger than Ru sites. |
| WOS关键词 | GENERALIZED GRADIENT APPROXIMATION ; SELECTIVE HYDRODEOXYGENATION ; PHENOLIC-COMPOUNDS ; CYCLOHEXANOL ; REDUCTION ; METHANE ; WATER |
| 资助项目 | Chinese National Natural Science Foundation ; Natural Science Foundation of Guangdong Province, China ; [52006074] ; [2021A1515010886] |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000880091200003 |
| 出版者 | ELSEVIER SCIENCE SA |
| 资助机构 | Chinese National Natural Science Foundation ; Natural Science Foundation of Guangdong Province, China |
| 源URL | [http://ir.giec.ac.cn/handle/344007/37868]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Xu, Xiwei |
| 作者单位 | 1.South China Agr Univ, Coll Mat & Energy, Key Lab Biobased Mat & Energy, Minist Educ, Guangzhou 510640, Peoples R China 2.North China Elect Power Univ, Natl Engn Lab Biomass Power Generat Equipment, Beijing 102206, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tu, Ren,Lv, Wei,Sun, Yan,et al. Ru-RuO2-Nb2O5/H beta zeolite catalyst for high-active hydrogenation of lignin derivatives at room temperature[J]. CHEMICAL ENGINEERING JOURNAL,2023,453:14. |
| APA | Tu, Ren.,Lv, Wei.,Sun, Yan.,Wu, Yujian.,Wu, Yangwen.,...&Xu, Xiwei.(2023).Ru-RuO2-Nb2O5/H beta zeolite catalyst for high-active hydrogenation of lignin derivatives at room temperature.CHEMICAL ENGINEERING JOURNAL,453,14. |
| MLA | Tu, Ren,et al."Ru-RuO2-Nb2O5/H beta zeolite catalyst for high-active hydrogenation of lignin derivatives at room temperature".CHEMICAL ENGINEERING JOURNAL 453(2023):14. |
入库方式： OAI收割
来源：广州能源研究所
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