Pristine and cobalt doped copper sulfide microsphere particles for seawater splitting
文献类型：期刊论文
| 作者 | Marimuthu, T.1,4; Yuvakkumar, R.1; Kumar, P. Senthil3,5; Ravi, G.1; Xu, Xueqing4; Xu, Gang4; Velauthapillai, Dhayalan2 |
| 刊名 | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
 |
| 出版日期 | 2022-10-30 |
| 卷号 | 47期号:88页码:37171-37182 |
| 关键词 | Hydrothermal CuS Microsphere Hydrogen evolution reaction Seawater splitting |
| ISSN号 | 0360-3199 |
| DOI | 10.1016/j.ijhydene.2021.09.172 |
| 通讯作者 | Yuvakkumar, R.(yuvakkumarr@alagappauniversity.ac.in) ; Kumar, P. Senthil(senthilkumarp@ssn.edu.in) ; Xu, Xueqing(xuxq@ms.giec.ac.cn) |
| 英文摘要 | In this work, copper sulfide particles are synthesized with different Co doping concen-trations such as 0, 1 and 5% at 80 degrees C by optimizing synthesis times from 1 to 3 h. Copper sulfide particles possess two structural phases of covellite CuS and digenite Cu9S5. The increase in synthesis time from 1 to 3 h increases the Cu9S5 phase growth and changes the morphology from flower to microsphere. The CuS synthesized with 0, 1 and 5% Co dopant concentrations demonstrate flower consisting of agglomerated nanosheets, microsphere and flower like microsphere. The elemental investigation substantiates Co ions presence in CuS microspheres. The A1g (LO) mode intensity is decreased with increase in Co dopant concentration confirming Co incorporation into CuS microsphere. The CuS synthesized with 0, 1, 5% Co dopants exhibit 322 mV, 305 mV and 289 mV to attain 100 mA/cm2 in 1 M KOH seawater. The CuS synthesized with 5% Co dopant demonstrates higher double layer capacitance (Cdl) of 173.9 mFcm-2 and lower charge transfer resistance (Rct) of 6.07 U with 78.84% retention after 10 h continuous stability than that of the other pristine (118.3 mFcm-2, 13.72 U) and 1% Co doped CuS microsphere (165.7 mFcm-2, 8.55 U) indicating more surface active site and rapid charge carrier transport, respectively.(c) 2021 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved. |
| WOS关键词 | HYDROGEN EVOLUTION REACTION ; BIFUNCTIONAL ELECTROCATALYSTS ; EFFICIENT ELECTROCATALYST ; NANOWIRE ARRAYS ; NICKEL FOAM ; CUS ; NANOPARTICLES ; PHOTOCATALYSTS ; PERFORMANCE ; FABRICATION |
| 资助项目 | UGC-SAP ; DST-FIST ; MHRD RUSA ; Project on Collaborative Innovation and Environmental Construction Platform of Guangdong Province[2018A050506067] |
| WOS研究方向 | Chemistry ; Electrochemistry ; Energy & Fuels |
| 语种 | 英语 |
| WOS记录号 | WOS:000889311300003 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 资助机构 | UGC-SAP ; DST-FIST ; MHRD RUSA ; Project on Collaborative Innovation and Environmental Construction Platform of Guangdong Province |
| 源URL | [http://ir.giec.ac.cn/handle/344007/37960]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Yuvakkumar, R.; Kumar, P. Senthil; Xu, Xueqing |
| 作者单位 | 1.Alagappa Univ, Dept Phys, Karaikkudi 630003, Tamil Nadu, India 2.Western Norway Univ Appl Sci, Fac Engn & Sci, N-5063 Bergen, Norway 3.Sri Sivasubramaniya Nadar Coll Engn, Ctr Excellence Water Res CEWAR, Chennai 603110, India 4.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 5.Sri Sivasubramaniya Nadar Coll Engn, Dept Chem Engn, Chennai 603110, India |
| 推荐引用方式 GB/T 7714 | Marimuthu, T.,Yuvakkumar, R.,Kumar, P. Senthil,et al. Pristine and cobalt doped copper sulfide microsphere particles for seawater splitting[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2022,47(88):37171-37182. |
| APA | Marimuthu, T..,Yuvakkumar, R..,Kumar, P. Senthil.,Ravi, G..,Xu, Xueqing.,...&Velauthapillai, Dhayalan.(2022).Pristine and cobalt doped copper sulfide microsphere particles for seawater splitting.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,47(88),37171-37182. |
| MLA | Marimuthu, T.,et al."Pristine and cobalt doped copper sulfide microsphere particles for seawater splitting".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 47.88(2022):37171-37182. |
入库方式： OAI收割
来源：广州能源研究所
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