Anodic Cross-Coupling of Biomass Platform Chemicals to Sustainable Biojet Fuel Precursors
文献类型：期刊论文
| 作者 | Wu, Jingcheng2,5; Xu, Leitao3,5; Li, Yingying5; Dong, Chung-Li4; Lu, Yuxuan5; Nga, Ta Thi Thuy4; Kong, Zhijie5; Li, Song1; Zou, Yuqin5; Wang, Shuangyin5 |
| 刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
 |
| 出版日期 | 2022-12-08 |
| 页码 | 8 |
| ISSN号 | 0002-7863 |
| DOI | 10.1021/jacs.2c11153 |
| 通讯作者 | Zou, Yuqin(yuqin_zou@hnu.edu.cn) ; Wang, Shuangyin(shuangyinwang@hnu.edu.cn) |
| 英文摘要 | Electrocatalytic conversion of biomass platform chemicals to jet fuel precursors is a promising approach to alleviate the energy crisis caused by the excessive exploitation and consumption of non-renewable fossil fuels. However, an aqueous electrolyte has been rarely studied. In this study, we demonstrate an anodic electrocatalysis route for producing jet fuel precursors from biomass platform chemicals on Ni-based electrocatalysts in an aqueous electrolyte at room temperature and atmosphere pressure. The desired product exhibited high selectivity for the jet fuel precursor (95.4%) and an excellent coulombic efficiency of 210%. A series of in situ characterizations demonstrated that Ni2+ species were the active sites for the coupling process. In addition, the coupling reaction could be achieved by generating radical cations and inhibiting the side reaction. First, the electrochemical process could activate the furfural (FF) molecule and generate radical cations, resulting in an average of 2.0 times chain propagation. The levulinic acid (LA) molecules played a vital role in the coupling reaction. The adsorption strength of LA on Ni3N was higher than that of FF, which could inhibit the side reaction (the oxidation of FF) and achieve high selectivity. Meanwhile, the LA molecules were adsorbed on the Ni3N surface and then disrupted the formation of Ni3+ species, thus favoring the coupling reaction. This work demonstrates an efficient route to produce jet fuel precursors directly from biomass platform chemicals and provides a comprehensive understanding of the anodic coupling process. |
| WOS关键词 | STRATEGIES ; OXIDATION ; FURAN |
| 资助项目 | National Key R&D Program of China ; National Natural Science Foundation of China ; Provincial Natural Science Foundation of Hunan ; China Postdoctoral Science Foundation ; [2020YFA0710000] ; [22122901] ; [21902047] ; [22109042] ; [2020JJ5045] ; [2021JJ20024] ; [2021RC3054] ; [2021 M701142] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000894508300001 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | National Key R&D Program of China ; National Natural Science Foundation of China ; Provincial Natural Science Foundation of Hunan ; China Postdoctoral Science Foundation |
| 源URL | [http://ir.giec.ac.cn/handle/344007/38063]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Zou, Yuqin; Wang, Shuangyin |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 2.Shanxi Normal Univ, Sch Chem & Mat Sci, Key Lab Magnet Mol & Magnet Informat Mat, Minist Educ, Taiyuan 030031, Shanxi, Peoples R China 3.Jishou Univ, Sch Chem & Chem Engn, Jishou 416000, Hunan, Peoples R China 4.Tamkang Univ, Dept Phys, New, Taipei, Peoples R China 5.Hunan Univ, Coll Chem & Chem Engn, Adv Catalyt Engn Res Ctr, Natl Supercomp Ctr Changsha,State Key Lab Chem Bio, Changsha 410082, Hunan, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu, Jingcheng,Xu, Leitao,Li, Yingying,et al. Anodic Cross-Coupling of Biomass Platform Chemicals to Sustainable Biojet Fuel Precursors[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2022:8. |
| APA | Wu, Jingcheng.,Xu, Leitao.,Li, Yingying.,Dong, Chung-Li.,Lu, Yuxuan.,...&Wang, Shuangyin.(2022).Anodic Cross-Coupling of Biomass Platform Chemicals to Sustainable Biojet Fuel Precursors.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,8. |
| MLA | Wu, Jingcheng,et al."Anodic Cross-Coupling of Biomass Platform Chemicals to Sustainable Biojet Fuel Precursors".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022):8. |
入库方式： OAI收割
来源：广州能源研究所
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