Liquid Membrane Catalysis Model for the Depolymerization of Single Particle Cellulose in a Gas-Liquid-Solid Multiphase System
文献类型：期刊论文
| 作者 | Sun, Weitao2,3; Wei, Xiangqian1; Zhang, Xinghua1; Li, Wenzhi3; Wei, Haoyang2; Liu, Siwei2; Ma, Longlong1 |
| 刊名 | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
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| 出版日期 | 2022-08-17 |
| 卷号 | 61期号:32页码:11996-12016 |
| ISSN号 | 0888-5885 |
| DOI | 10.1021/acs.iecr.2c01570 |
| 通讯作者 | Wei, Xiangqian(xq66@mail.ustc.edu.cn) ; Zhang, Xinghua(zhangxh@seu.edu.cn) ; Ma, Longlong(mall@seu.edu.cn) |
| 英文摘要 | 5-Hydroxymethylfurfural (HMF) produced from the hydrolyzation of cellulose has received significant attention. The liquid-membrane-catalyzed hydrolyzation of cellulose to obtain HMF is a gas-liquid-solid reaction system that involves complex physicochemical phenomena. For the simulation of the preparation of HMF from cellulose, this article developed a liquid membrane catalytic model based on the Shan-Chen pseudopotential model of the multiphase lattice Boltzmann method. Multiphase liquid membrane catalysis model captures well the interfacial multicomponent mass transport and the interface characteristics of the liquid membrane and cellulose wall. The system also undergoes heterogeneous reactions, and the cellulose particles react with each other. It has been established that cellulose hydrolysis and liquid membrane thickness (delta(xi)) are coupled mechanisms. HMF yield was negatively impacted by delta(xi). The final HMF yield shows an approximate linear relation with d.. Furthermore, an influence factor of the initial thickness of liquid membrane Omega(ss) was proposed to characterize the impact intensity of delta(xi) on the final yield of HMF. Besides, with reaction temperature, a significant increasing trend of Omega(ss) was found. A study of the interface mass transport mechanism, heterogeneous reactions, and the evolution of the liquid-solid interface was conducted, and the results obtained may aid in the efficient transformation of cellulose. |
| WOS关键词 | GLUCOSE ISOMERIZATION ; BIOMASS ; CONVERSION ; TRANSPORT ; CHEMICALS ; MECHANISM ; FLOWS |
| 资助项目 | National Natural Science Foundation of China[51876210] ; National Natural Science Foundation of China[51976220] ; National Key R&D program of China[2018 YFB1501402] |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000895746500001 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | National Natural Science Foundation of China ; National Key R&D program of China |
| 源URL | [http://ir.giec.ac.cn/handle/344007/38066]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Wei, Xiangqian; Zhang, Xinghua; Ma, Longlong |
| 作者单位 | 1.Southeast Univ, Sch Energy & Environm, Key Lab Energy Thermal Convers & Proc Meausrement, Minist Educ, Nanjing 210096, Jiangsu, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 3.Univ Sci & Technol China, Dept Thermal Sci & Energy Engn, Lab Basic Res Biomass Convers & Utilizat, Hefei 230026, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun, Weitao,Wei, Xiangqian,Zhang, Xinghua,et al. Liquid Membrane Catalysis Model for the Depolymerization of Single Particle Cellulose in a Gas-Liquid-Solid Multiphase System[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2022,61(32):11996-12016. |
| APA | Sun, Weitao.,Wei, Xiangqian.,Zhang, Xinghua.,Li, Wenzhi.,Wei, Haoyang.,...&Ma, Longlong.(2022).Liquid Membrane Catalysis Model for the Depolymerization of Single Particle Cellulose in a Gas-Liquid-Solid Multiphase System.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,61(32),11996-12016. |
| MLA | Sun, Weitao,et al."Liquid Membrane Catalysis Model for the Depolymerization of Single Particle Cellulose in a Gas-Liquid-Solid Multiphase System".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 61.32(2022):11996-12016. |
入库方式： OAI收割
来源：广州能源研究所
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