Efficient Adsorption of a Sulfonamide Antibiotic in Aqueous Solutions with N-doped Magnetic Biochar: Performance, Mechanism, and Reusability
文献类型：期刊论文
| 作者 | Diao, Yuan1,2; Shan, Rui2,3; Li, Mei1; Gu, Jing2,3; Yuan, Haoran2,3; Chen, Yong2,3 |
| 刊名 | ACS OMEGA
 |
| 出版日期 | 2022-12-21 |
| 页码 | 14 |
| ISSN号 | 2470-1343 |
| DOI | 10.1021/acsomega.2c06234 |
| 通讯作者 | Yuan, Haoran(yuanhr@ms.giec.ac.cn) |
| 英文摘要 | Conventional biochar has limited effectiveness in the adsorption of sulfonamide antibiotics, while modified biochar exhibits greater adsorption potential. Residues of sulfamethoxazole (SMX) in the aquatic environment can threaten the safety of microbial populations as well as humans. In this study, iron- nitrogen co-doped modified biochar (Fe-N-BC) was prepared from palm fibers and doped with Fe and urea via synthesis at 500 degrees C. Fe-N-BC has a richer surface functional group based on elemental content, X-ray photoelectron spectroscopy, Xray diffraction, and Fourier transform infrared spectroscopy. The Brunauer- Emmett-Teller (BET) specific surface area test exhibited Fe-N-BC, which possessed a greater surface area (318.203 m2/g) and a better developed pore structure (0.149 cm3/g). The results of the hysteresis loop and the Raman spectrum show that Fe-N-BC has a higher degree of magnetization and graphitization. Fe-N-BC showed a remarkable adsorption capacity for SMX (42.9 mg/g), which could maintain 93.4% adsorption effect after four cycles, and 82.8% adsorption capacity in simulated piggery wastewater. The adsorption mechanism involves pore filling, surface complexation, electrostatic interactions, hydrogen bonding, and pi-pi EDA interactions. The results of this study show that Fe-N-BC prepared from palm fibers can be a stable, excellent adsorbent for SMX removal from wastewater and has promise in terms of practical applications. |
| WOS关键词 | REMOVAL |
| 资助项目 | State?s Key Project of Research and Development Plan, China ; Science and Technology Program of Guangdong Province, China ; Science and Technology Program of Guangzhou, China ; Guangdong Basic and Applied Basic Research Foundation ; [2020YFC1908900] ; [2021A1515012263] ; [202002030365] ; [2021B1515020068] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000904089300001 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | State?s Key Project of Research and Development Plan, China ; Science and Technology Program of Guangdong Province, China ; Science and Technology Program of Guangzhou, China ; Guangdong Basic and Applied Basic Research Foundation |
| 源URL | [http://ir.giec.ac.cn/handle/344007/38158]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Yuan, Haoran |
| 作者单位 | 1.Shandong Jianzhu Univ, Sch Municipal & Environm Engn, Jinan 250000, Shandong, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 3.CAS Key Lab Renewable Energy, Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China |
| 推荐引用方式 GB/T 7714 | Diao, Yuan,Shan, Rui,Li, Mei,et al. Efficient Adsorption of a Sulfonamide Antibiotic in Aqueous Solutions with N-doped Magnetic Biochar: Performance, Mechanism, and Reusability[J]. ACS OMEGA,2022:14. |
| APA | Diao, Yuan,Shan, Rui,Li, Mei,Gu, Jing,Yuan, Haoran,&Chen, Yong.(2022).Efficient Adsorption of a Sulfonamide Antibiotic in Aqueous Solutions with N-doped Magnetic Biochar: Performance, Mechanism, and Reusability.ACS OMEGA,14. |
| MLA | Diao, Yuan,et al."Efficient Adsorption of a Sulfonamide Antibiotic in Aqueous Solutions with N-doped Magnetic Biochar: Performance, Mechanism, and Reusability".ACS OMEGA (2022):14. |
入库方式： OAI收割
来源：广州能源研究所
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