Selective CO2 Hydrogenation to Light Aromatics over the Cu-Modified Fe-Based/ZSM-5 Catalyst System
文献类型：期刊论文
| 作者 | Wen, Chengyan1; Xu, Xianglong1; Song, Xiangbo2; Lu, Luying3; Zhuang, Xiuzheng1; Jin, Ke3; Jiang, Qian3; Zhang, Xinghua1; Chen, Lungang1; Wang, Chenguang3 |
| 刊名 | ENERGY & FUELS
 |
| 出版日期 | 2022-12-20 |
| 页码 | 11 |
| ISSN号 | 0887-0624 |
| DOI | 10.1021/acs.energyfuels.2c03414 |
| 通讯作者 | Zhang, Xinghua(zhangxh@seu.edu.cn) ; Wang, Chenguang(wangcg@ms.giec.ac.cn) ; Ma, Longlong(mall@seu.edu.cn) |
| 英文摘要 | Direct CO2 hydrogenation to value-added chemicals not only decreases carbon emissions but also provides an alternative way for fossil fuels. Even though some outstanding results were obtained, the high productivity of the target product is still hard to achieve. In this work, we fabricated a bifunctional catalyst comprising a Cu-modified Fe-based catalyst and ZSM-S for selective CO2 hydrogenation to aromatics with the help of XRD, H-2-TPR, CO2-TPD, SEM, TEM and N-2 adsorption and desorption techniques for the catalytic mechanism of the prepared catalysts. The results show that the Cu promoter can improve the carbonchain growth, suppress methane formation over the Fe-based catalyst, and then increase the aromatic selectivity over the bifunctional catalyst, suggesting that heavy olefin-based intermediates are more prone to aromatization than light intermediates. By lengthening the straight channel length of zeolites in the direction of the b-axis, a STY(toulence )of 14.8 g(CH2).kg(cat)(-1).h(-1) is obtained. The relevant mechanism may be attributed to the increase in the b-axis length, which restricts the diffusion of products on the straight channel, forcing the product to diffuse from the sinusoidal channel in the ZSM-5 zeolite. This work provides insights for designing a bifunctional catalyst that achieves high productivity of high value-added aromatics. |
| WOS关键词 | CARBON-DIOXIDE ; DIRECT TRANSFORMATION ; DIRECT CONVERSION ; SYNGAS |
| 资助项目 | Postgraduate Research & Practice Innovation Program of Jiangsu Province ; Fundamental Research Funds for the Central Universities ; National Natural Science Foundation of China ; National Key R&D Program of China ; [KYCX20_0095] ; [3203002104D] ; [51776206] ; [21878290] ; [2018YFB1501504] ; [2019YFD1100601] |
| WOS研究方向 | Energy & Fuels ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000901860600001 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | Postgraduate Research & Practice Innovation Program of Jiangsu Province ; Fundamental Research Funds for the Central Universities ; National Natural Science Foundation of China ; National Key R&D Program of China |
| 源URL | [http://ir.giec.ac.cn/handle/344007/38161]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Zhang, Xinghua; Wang, Chenguang; Ma, Longlong |
| 作者单位 | 1.Southeast Univ, Sch Energy & Environm, Nanjing 210009, Peoples R China 2.Chuxiong Normal Univ, Sch Phys & Elect Sci, Chuxiong 675000, Yunnan, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wen, Chengyan,Xu, Xianglong,Song, Xiangbo,et al. Selective CO2 Hydrogenation to Light Aromatics over the Cu-Modified Fe-Based/ZSM-5 Catalyst System[J]. ENERGY & FUELS,2022:11. |
| APA | Wen, Chengyan.,Xu, Xianglong.,Song, Xiangbo.,Lu, Luying.,Zhuang, Xiuzheng.,...&Ma, Longlong.(2022).Selective CO2 Hydrogenation to Light Aromatics over the Cu-Modified Fe-Based/ZSM-5 Catalyst System.ENERGY & FUELS,11. |
| MLA | Wen, Chengyan,et al."Selective CO2 Hydrogenation to Light Aromatics over the Cu-Modified Fe-Based/ZSM-5 Catalyst System".ENERGY & FUELS (2022):11. |
入库方式： OAI收割
来源：广州能源研究所
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