Novel Biosurfactants for Effective Inhibition of Gas Hydrate Agglomeration and Corrosion in Offshore Oil and Gas Pipelines
文献类型：期刊论文
| 作者 | Tang, Cuiping2; Farhadian, Abdolreza1,9; Berisha, Avni3,4; Deyab, Mohamed A.5; Chen, Jie6; Iravani, Danial7; Rahimi, Alireza8; Zhang, Zhengcai6; Liang, Deqing2 |
| 刊名 | ACS SUSTAINABLE CHEMISTRY & ENGINEERING
 |
| 出版日期 | 2022-12-27 |
| 页码 | 15 |
| 关键词 | oleic acid flow assurance gas hydrate inhibitor corrosion inhibitor compatibility issue |
| ISSN号 | 2168-0485 |
| DOI | 10.1021/acssuschemeng.2c05716 |
| 通讯作者 | Farhadian, Abdolreza(AFarhadian@kpfu.ru) ; Liang, Deqing(liangdq@ms.giec.ac.cn) |
| 英文摘要 | Gas hydrate and corrosion inhibitors are widely used to ensure a successful and economic hydrocarbon stream flow inside oil and gas pipelines. However, compatibility problems are observed during their co-injection into the flowlines as they have different molecular chemistry. Using anti-agglomerant hydrate inhibitors is an effective method to control the gas hydrate plugging risk in deep-water hydrocarbon flow lines or throughout drilling operations. Here, oleic acid was used to develop the first class of biosurfactants as anti-agglomerant and corrosion inhibitors using click chemistry for flow assurance applications. The results of high-pressure autoclave showed that both bio-based anti-agglomerants (BAAs) significantly inhibited gas hydrate agglomeration, and the value of torque remained constant during the hydrate formation process. The hydrate particles were effectively dispersed in liquid paraffin in the presence of 1 wt % of BAA1 or BAA2. In addition, molecular dynamic simulation revealed that the headgroup of BAA1 was adsorbed on the hydrate surface, and its alkyl chain dispersed the hydrate formed in the hydrocarbon phase as a slurry. According to electrochemical measurements, both BAAs were highly efficient inhibitors for the prevention of mild steel corrosion in saturated H2S and CO2-simulated oilfield water. BAA1 and BAA2 completely protected the steel in the corrosive medium by 99 and 98.8%, respectively, at 0.1 wt %. Moreover, the adsorption of BAA1 molecules on the steel surface was both physically and chemically in a direction that was almost parallel to the surface. Such adsorption provides the maximum surface coverage against corrosion. These findings suggest that oleic acid can be used as a potential starting material to develop eco-friendly inhibitors for flow assurance in oil and gas pipelines. |
| WOS关键词 | MILD-STEEL ; PLUG PREVENTION ; SUNFLOWER OIL ; CARBON-STEEL ; SCHIFF-BASE ; HCL ; SURFACTANT ; FIELD ; POLYURETHANE ; ADSORPTION |
| 资助项目 | Shahid Beheshti University ; Research Institute of Petroleum Industry ; National Natural Science Foundation of China[51876211] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000906481900001 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | Shahid Beheshti University ; Research Institute of Petroleum Industry ; National Natural Science Foundation of China |
| 源URL | [http://ir.giec.ac.cn/handle/344007/38186]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Farhadian, Abdolreza; Liang, Deqing |
| 作者单位 | 1.Kazan Fed Univ, Dept Petr Engn, Kazan 420008, Russia 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 3.Univ Prishtina, Fac Nat & Math Sci, Dept Chem, Prishtina 10000, Kosovo 4.NanoAlb Unit Albanian Nanosci & Nanotechnol, Mat Sci Nanochem Res Grp, Tirana 1000, Albania 5.Egyptian Petr Res Inst EPRI, Nasr City 11727, Egypt 6.Qingdao Natl Lab Marine Sci & Technol, Lab Marine Mineral Resources, Qingdao 266237, Peoples R China 7.Ferdowsi Univ Mashhad, Fac Engn, Chem Engn Dept, Mashhad 9177948974, Iran 8.Res Inst Petr Ind RIPI, Fac Res & Dev Energy & Environm, Tehran 1485733111, Iran 9.Shahid Beheshti Univ, Fac Chem & Petr Sci, Dept Polymer & Mat Chem, Tehran 1983969411, Iran |
| 推荐引用方式 GB/T 7714 | Tang, Cuiping,Farhadian, Abdolreza,Berisha, Avni,et al. Novel Biosurfactants for Effective Inhibition of Gas Hydrate Agglomeration and Corrosion in Offshore Oil and Gas Pipelines[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2022:15. |
| APA | Tang, Cuiping.,Farhadian, Abdolreza.,Berisha, Avni.,Deyab, Mohamed A..,Chen, Jie.,...&Liang, Deqing.(2022).Novel Biosurfactants for Effective Inhibition of Gas Hydrate Agglomeration and Corrosion in Offshore Oil and Gas Pipelines.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,15. |
| MLA | Tang, Cuiping,et al."Novel Biosurfactants for Effective Inhibition of Gas Hydrate Agglomeration and Corrosion in Offshore Oil and Gas Pipelines".ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2022):15. |
入库方式： OAI收割
来源：广州能源研究所
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