Graphene Encapsulated Low-Load Nitrogen-Doped Bimetallic Magnetic Pd/Fe@N/C Catalyst for the Reductive Amination of Nitroarene Under Mild Conditions
文献类型：期刊论文
| 作者 | Lin, Shanshan1,2; Liu, Jianguo3; Ma, Longlong3 |
| 刊名 | CATALYSIS LETTERS
 |
| 出版日期 | 2023-01-20 |
| 页码 | 12 |
| 关键词 | Nitrobenzene Aniline Hydrogenation Heterogeneous catalyst Transition metals Graphene shelled catalyst |
| ISSN号 | 1011-372X |
| DOI | 10.1007/s10562-023-04273-7 |
| 通讯作者 | Liu, Jianguo(liujg@seu.edu.cn) |
| 英文摘要 | Aniline is a group of important platform molecules that has been widely used in the synthesis of other high-value chemicals and pharmaceutical products. How to produce high-value anilines as the high-value chemical intermediates more efficiently and environmentally has always been a research topic in the industry. Catalytic hydrogenation is an environmentally friendly method for preparing halogenated anilines. Traditional noble metal catalysts face the problems of cost and noble metals residue. To improve the purity of the product as well as the activity and recyclability of the catalyst, we prepared a Pd/Fe magnetic bimetallic catalyst supported on N-doped carbon materials to reduce nitrobenzene to aniline under mild conditions. The catalyst has a low Pd loading of 2.35%. And the prepared bimetallic Pd/Fe@N/C catalyst showed excellent catalytic reactivity with the nitrobenzene conversion rate of 99%, and the aniline selectivity of 99% under mild reaction conditions of 0.8 MPa H-2 and 40 & DEG;C. A variety of halogenated and aliphatic nitro compounds were well tolerated and had been transformed to the corresponding target amine products with excellent selectivity. In addition, the novel N-doped graphene-encapsulated bimetallic magnetic Pd/Fe@N/C catalyst not only had magnetic physical properties, which was easy to separate, recover, and used for the recycling of the catalyst without metal leaching but also catalyzed highly selective reductive amination of aromatics was a green, economical and environmentally friendly reaction with the only by-product of H2O. |
| WOS关键词 | SELECTIVE HYDROGENATION ; GALVANIC DISPLACEMENT ; CARBON ; NANOPARTICLES ; NITROBENZENE ; PERFORMANCE ; ULTRAFINE ; ANILINES ; BONDS |
| 资助项目 | National Natural Science Foundation of China[52236010] ; National Natural Science Foundation of China[51976225] ; Fundamental Research Funds for the Central Universities[2242022R10058] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000920391500002 |
| 出版者 | SPRINGER |
| 资助机构 | National Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities |
| 源URL | [http://ir.giec.ac.cn/handle/344007/38392]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Liu, Jianguo |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 3.Southeast Univ, Sch Energy & Environm, Key Lab Energy Thermal Convers & Control, Minist Educ, Nanjing 210096, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lin, Shanshan,Liu, Jianguo,Ma, Longlong. Graphene Encapsulated Low-Load Nitrogen-Doped Bimetallic Magnetic Pd/Fe@N/C Catalyst for the Reductive Amination of Nitroarene Under Mild Conditions[J]. CATALYSIS LETTERS,2023:12. |
| APA | Lin, Shanshan,Liu, Jianguo,&Ma, Longlong.(2023).Graphene Encapsulated Low-Load Nitrogen-Doped Bimetallic Magnetic Pd/Fe@N/C Catalyst for the Reductive Amination of Nitroarene Under Mild Conditions.CATALYSIS LETTERS,12. |
| MLA | Lin, Shanshan,et al."Graphene Encapsulated Low-Load Nitrogen-Doped Bimetallic Magnetic Pd/Fe@N/C Catalyst for the Reductive Amination of Nitroarene Under Mild Conditions".CATALYSIS LETTERS (2023):12. |
入库方式： OAI收割
来源：广州能源研究所
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