New insights into the degradation and detoxification of methylene blue using heterogeneous-Fenton catalyzed by sustainable siderite
文献类型：期刊论文
| 作者 | Fu, Caixia3; Yan, Miao3; Wang, Zhuoyue1,2; Li, Ji2; Zhang, Xiaolei2; Song, Wei1; Xu, Zhiliang2; Bhatt, Kalpana4; Wang, Zhongming3; Zhu, Shunni3 |
| 刊名 | ENVIRONMENTAL RESEARCH
 |
| 出版日期 | 2023 |
| 卷号 | 216页码:10 |
| 关键词 | Siderite/H2O2 process Methylene blue Adsorption Oxidation Degradation pathway Detoxification |
| ISSN号 | 0013-9351 |
| DOI | 10.1016/j.envres.2022.114819 |
| 通讯作者 | Song, Wei(sw_hitsz@foxmail.com) |
| 英文摘要 | The huge application of synthetic dyes caused a severe impact in the environment. In the present study, a physico-chemical strategy of heterogeneous-Fenton catalyzed by the natural ferrous ore has been established for toxic chemical degradation, of which the complex and high-expense repetitive pH adjustment procedures were escaping. And this natural heterogeneous catalyst also could be recycled and sustainable for toxic substances treatment involved in synergetic adsorption and oxidation. The siderite, served as an adsorbent and catalyst for the degradation of methylene blue (MB). Siderite exhibited a better adsorption capacity with a saturated adsorption capacity of similar to 11.08 mg/g. Batch adsorption experiments have verified that adsorption rate and adsorption equilibrium followed pseudo-second-order rate model and Langmuir isotherm equation, respectively. The combination with H2O2, showed significant enhancement of MB degradation without any pH adjustment. The effect of siderite dosage, H2O2 dosage, MB concentration, initial pH, and reaction temperature on MB degradation was investigated, which also has indicated the excellent catalytic performance of siderite. About 99.71% of MB was degraded in 480 min with initial pH of 7.0, reaction temperature of 25 degrees C, siderite, and H2O2 dosage of 2.5 g/L and 122.38 mM, respectively. It was found that siderite could be reused and remained high degradation efficiency on MB after 5 times reutilization, which also could demonstrate the sustainable and effective process to degrade organic pollution. The generation of reactive species including center dot OH and O2 center dot- have been confirmed based on scavenger test and electron spin resonance (ESR) analysis, which was dominated by heterogeneous reaction. The possible degradation mechanisms of MB have been predicted based on spectrum scanning and GC-MS analysis. Moreover, acute toxicity assessment with marine photobacterium Vibrio fisheri was conducted to investigate the toxicity change in the adsorption/oxidation coupled process. This sustainable heterogeneous-Fenton technology has been verified as a promising and applicable process for toxic organic chemicals removal due to effective mineralization and detoxification assisted with the natural ore mineral through the simple operation and mild condtions. |
| WOS关键词 | ADVANCED OXIDATION ; DYE ; ADSORPTION ; REMOVAL ; WATER ; MECHANISM ; KINETICS ; CARBON ; OXIDE ; FE |
| 资助项目 | National Natural Science Foundation of China ; Shenzhen Sustainable Development Project ; [52200088] ; [KCXFZ20201221173602008] |
| WOS研究方向 | Environmental Sciences & Ecology ; Public, Environmental & Occupational Health |
| 语种 | 英语 |
| WOS记录号 | WOS:000918196300001 |
| 出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
| 资助机构 | National Natural Science Foundation of China ; Shenzhen Sustainable Development Project |
| 源URL | [http://ir.giec.ac.cn/handle/344007/38506]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Song, Wei |
| 作者单位 | 1.Guangdong Univ Technol, Sch Civil & Transportat Engn, Guangzhou 510006, Peoples R China 2.Harbin Inst Technol Shenzhen, Sch Civil & Environm Engn, Shenzhen Key Lab Water Resource Applicat & Environ, Shenzhen 518055, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 4.Purdue Univ, Dept Food Sci, W Lafayette, IN 47907 USA |
| 推荐引用方式 GB/T 7714 | Fu, Caixia,Yan, Miao,Wang, Zhuoyue,et al. New insights into the degradation and detoxification of methylene blue using heterogeneous-Fenton catalyzed by sustainable siderite[J]. ENVIRONMENTAL RESEARCH,2023,216:10. |
| APA | Fu, Caixia.,Yan, Miao.,Wang, Zhuoyue.,Li, Ji.,Zhang, Xiaolei.,...&Zhu, Shunni.(2023).New insights into the degradation and detoxification of methylene blue using heterogeneous-Fenton catalyzed by sustainable siderite.ENVIRONMENTAL RESEARCH,216,10. |
| MLA | Fu, Caixia,et al."New insights into the degradation and detoxification of methylene blue using heterogeneous-Fenton catalyzed by sustainable siderite".ENVIRONMENTAL RESEARCH 216(2023):10. |
入库方式： OAI收割
来源：广州能源研究所
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