One-pot synthesis of Fe x O y nanoparticles emb e dde d within N-doped carbon layers as highly efficient and selective catalysts for the hydrogenation of nitroarenes
文献类型：期刊论文
| 作者 | Zhuang, Xiuzheng2; Jin, Ke1; Zhang, Qi2; Liu, Jianguo2; Zhang, Xinghua2; Zhan, Hao3; Ma, Longlong2 |
| 刊名 | CHINESE CHEMICAL LETTERS
 |
| 出版日期 | 2023-06-01 |
| 卷号 | 34期号:6页码:6 |
| 关键词 | Facile synthesis Iron-based catalyst Carbonaceous layers Nitroarenes reduction |
| ISSN号 | 1001-8417 |
| DOI | 10.1016/j.cclet.2022.107954 |
| 通讯作者 | Ma, Longlong(mall@seu.edu.cn) |
| 英文摘要 | Inhibiting the side reactions while promoting hydrogenation are the main target for the production of functional anilines from nitroarenes; consequently, the preparation of an ideal catalyst to improve chemical selectivity is one of the hot issues. In this work, we provided an easy-to-prepare catalyst with Ndoped carbon layers, where the FexOy nanoparticles were encapsulated and distributed uniformly. The structural features of catalyst were characterized by several techniques, and the selected catalyst was next applied to the hydrogenation of nitrobenzene under varied conditions, involving temperature, holding period and H2 pressure. Subsequently, we conducted the synthesis of more than 16 substrates for the corresponding anilines with varied functional groups. The hydrogenation protocol to gram-scale synthesis as well as lifecycle performance were also demonstrated in the batch reactor, together with the explanation of its catalytic mechanisms. Overall, the present work provides an available preparation of simple but highly efficient catalysts for the production or aromatic amines, which will be benefit for the sustainable development of this field in near future.(c) 2023 Published by Elsevier B.V. on behalf of Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. |
| WOS关键词 | POROUS CARBON ; NITROBENZENE ; REDUCTION |
| 资助项目 | National Natural Science Foundation of China[52236010] ; National Natural Science Foundation of China[51876209] ; National Natural Science Foundation of China[51906247] ; Fundamental Research Funds for the Central Universities[51876210] ; [2242022R10058] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:001000298100001 |
| 出版者 | ELSEVIER SCIENCE INC |
| 资助机构 | National Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities |
| 源URL | [http://ir.giec.ac.cn/handle/344007/38946]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Ma, Longlong |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 2.Southeast Univ, Sch Energy & Environm, Key Lab Energy Thermal Convers & Control, Minist Educ, Nanjing 210096, Peoples R China 3.Cent South Univ, Sch Energy Sci & Engn, Changsha 410083, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhuang, Xiuzheng,Jin, Ke,Zhang, Qi,et al. One-pot synthesis of Fe x O y nanoparticles emb e dde d within N-doped carbon layers as highly efficient and selective catalysts for the hydrogenation of nitroarenes[J]. CHINESE CHEMICAL LETTERS,2023,34(6):6. |
| APA | Zhuang, Xiuzheng.,Jin, Ke.,Zhang, Qi.,Liu, Jianguo.,Zhang, Xinghua.,...&Ma, Longlong.(2023).One-pot synthesis of Fe x O y nanoparticles emb e dde d within N-doped carbon layers as highly efficient and selective catalysts for the hydrogenation of nitroarenes.CHINESE CHEMICAL LETTERS,34(6),6. |
| MLA | Zhuang, Xiuzheng,et al."One-pot synthesis of Fe x O y nanoparticles emb e dde d within N-doped carbon layers as highly efficient and selective catalysts for the hydrogenation of nitroarenes".CHINESE CHEMICAL LETTERS 34.6(2023):6. |
入库方式： OAI收割
来源：广州能源研究所
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