Synthesis of high-density bio-jet fuel by one-pot Mannich-Michael reaction and subsequent hydrodeoxygenation over alkali-treated zeolite catalysts
文献类型：期刊论文
| 作者 | Kang, Qixiang1,3; Zhang, Xinghua1; Cui, Yanyan2,3; Zhao, Xuelai3; Wang, Wuyu1; Zhang, Jiapeng3; Zhang, Qi1; Ma, Longlong1 |
| 刊名 | FUEL
 |
| 出版日期 | 2023-10-01 |
| 卷号 | 349页码:9 |
| 关键词 | Biomass High-density fuel Mannich reaction Michael reaction Enamine mechanism Alkaline treatment |
| ISSN号 | 0016-2361 |
| DOI | 10.1016/j.fuel.2023.128706 |
| 通讯作者 | Zhang, Xinghua(zhangxh@seu.edu.cn) ; Ma, Longlong(mall@seu.edu.cn) |
| 英文摘要 | Cycloalkanes jet fuel with high-density derived from biomass are the ideal alternative to fossil fuel. The one-pot Mannich-Michael reaction of cyclopentanone and formaldehyde followed by hydrodeoxygenation (HDO) is a prospective route for the synthesis of cyclic high-density jet fuel. The synergistic interaction of pyrrolidine with acetic acid exhibited high catalytic activity in the one-pot Mannich-Michael reaction under mild conditions (50 celcius, 6 h). Additionally, solvents with appropriate polarity promote proton transfer to form Mannich bases, which are subsequently decomposed to produce 2-methylenecyclopentanone as the substrate for Michael addition. Thus, a high yield of condensed products (92.3%) with 93.3% conversion of cyclopentanone was obtained via an enamine catalytic pathway. The alkali-treated H beta 25-1 combined with Pd/C effectively catalyze the HDO of condensate products. The alkali-treated H beta 25-1 with larger mesoporous volume and sufficient acid sites lead to a high yield of dicyclopentylmethane (73.6%). The density and heating value of the HDO liquid products were 0.906 g/cm3 and 40.5 MJ/L, respectively. This work provided a novel route for high-density jet-fuel from lignocellulosic platform compounds. |
| WOS关键词 | HYDROLYSIS ; CONVERSION ; LIGNOCELLULOSE ; DESILICATION ; PERFORMANCE ; CELLULOSE ; BIOFUEL ; ACIDITY ; KETONES |
| 资助项目 | National Key R&D Program of China[2022YFB4201803] ; National Natural Science Foun-dation of China[52236010] ; Academician and Expert Work-station of Yunnan Province, China[202205AF150024] ; Jiangsu Provincial Double-Innovation Doctor Program[JSSCBS20220178] ; Fundamental Research Funds for the Central Universities[2242022R10058] |
| WOS研究方向 | Energy & Fuels ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:001007208200001 |
| 出版者 | ELSEVIER SCI LTD |
| 资助机构 | National Key R&D Program of China ; National Natural Science Foun-dation of China ; Academician and Expert Work-station of Yunnan Province, China ; Jiangsu Provincial Double-Innovation Doctor Program ; Fundamental Research Funds for the Central Universities |
| 源URL | [http://ir.giec.ac.cn/handle/344007/39043]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Zhang, Xinghua; Ma, Longlong |
| 作者单位 | 1.Southeast Univ, Sch Energy & Environm, Minist Educ, Key Lab Energy Thermal Convers & Proc Measurement, Nanjing 210096, Jiangsu, Peoples R China 2.Univ Sci & Technol China, Nano Sci & Technol Inst, Suzhou 215123, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China |
| 推荐引用方式 GB/T 7714 | Kang, Qixiang,Zhang, Xinghua,Cui, Yanyan,et al. Synthesis of high-density bio-jet fuel by one-pot Mannich-Michael reaction and subsequent hydrodeoxygenation over alkali-treated zeolite catalysts[J]. FUEL,2023,349:9. |
| APA | Kang, Qixiang.,Zhang, Xinghua.,Cui, Yanyan.,Zhao, Xuelai.,Wang, Wuyu.,...&Ma, Longlong.(2023).Synthesis of high-density bio-jet fuel by one-pot Mannich-Michael reaction and subsequent hydrodeoxygenation over alkali-treated zeolite catalysts.FUEL,349,9. |
| MLA | Kang, Qixiang,et al."Synthesis of high-density bio-jet fuel by one-pot Mannich-Michael reaction and subsequent hydrodeoxygenation over alkali-treated zeolite catalysts".FUEL 349(2023):9. |
入库方式： OAI收割
来源：广州能源研究所
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