Oxidative Catalytic Fractionation of Lignocellulose to High-Yield Aromatic Aldehyde Monomers and Pure Cellulose
文献类型：期刊论文
| 作者 | Zhu, Yuting1,2; Liao, Yuhe1; Lu, Luying1,2; Lv, Wei1; Liu, Jing1,2; Song, Xiangbo1,2; Wu, Jingcheng1,2; Li, Lei3; Wang, Chenguang1; Ma, Longlong1 |
| 刊名 | ACS CATALYSIS
 |
| 出版日期 | 2023-05-30 |
| 卷号 | 13期号:12页码:7929-7941 |
| 关键词 | lignin vanillin cellulose oxidativecatalytic fractionation CuO |
| ISSN号 | 2155-5435 |
| DOI | 10.1021/acscatal.3c01309 |
| 通讯作者 | Wang, Chenguang(wangcg@ms.giec.ac.cn) ; Sels, Bert F.(bert.sels@kuleuven.be) |
| 英文摘要 | Facileoxidation is a promising technology to valorize lignocellulosicbiomass toward high-value chemicals and cellulose. However, the carbonefficiency is restricted by inevitable dissolution and conversionof carbohydrates and the condensation and degradation of lignin andmonophenolics. Herein, we report the use of CuO nanoparticles (NPs)to oxidatively fractionate lignocellulose with O-2 in aqueousNaOH under mild conditions, achieving over 80% carbon efficiency.Lignin was converted to aromatic aldehyde monomers (up to 48.6 wt%, mainly vanillin and syringaldehyde), and the yield can surpassthe theoretical value (on the basis of the beta-O-4 bond content)due to cleavage of other bonds. This was proven by several model compoundswith different interlinkages. All hemicelluloses were transformedtoward water-soluble small acids (mainly oxalic acid). As it was protectedby the complexation of Cu cations, up to 80% cellulose was obtainedas a white crystalline residue with high purity (>95%), which haspotential applications in the production of materials and chemicals. |
| WOS关键词 | LIGNIN DEPOLYMERIZATION ; PINE WOOD ; CHEMICALS ; BIOMASS ; CONVERSION ; VANILLIN ; ACIDS |
| 资助项目 | National Natural Science Foundation of China[22208338] ; R&D Plan of Key Fields in Guangdong Province[2020B1111570001] ; National Key R&D Program of China[2018YFB1501504] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:001008895000001 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | National Natural Science Foundation of China ; R&D Plan of Key Fields in Guangdong Province ; National Key R&D Program of China |
| 源URL | [http://ir.giec.ac.cn/handle/344007/39046]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Wang, Chenguang; Sels, Bert F. |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Jinan Univ, Atmospher Environm Inst Safety & Pollut Control, Guangzhou 510632, Peoples R China 4.Katholieke Univ Leuven, Ctr Sustainable Catalysis & Engn, B-3001 Leuven, Belgium |
| 推荐引用方式 GB/T 7714 | Zhu, Yuting,Liao, Yuhe,Lu, Luying,et al. Oxidative Catalytic Fractionation of Lignocellulose to High-Yield Aromatic Aldehyde Monomers and Pure Cellulose[J]. ACS CATALYSIS,2023,13(12):7929-7941. |
| APA | Zhu, Yuting.,Liao, Yuhe.,Lu, Luying.,Lv, Wei.,Liu, Jing.,...&Sels, Bert F..(2023).Oxidative Catalytic Fractionation of Lignocellulose to High-Yield Aromatic Aldehyde Monomers and Pure Cellulose.ACS CATALYSIS,13(12),7929-7941. |
| MLA | Zhu, Yuting,et al."Oxidative Catalytic Fractionation of Lignocellulose to High-Yield Aromatic Aldehyde Monomers and Pure Cellulose".ACS CATALYSIS 13.12(2023):7929-7941. |
入库方式： OAI收割
来源：广州能源研究所
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