Antibiotic residue derived solid acids for ethanolysis of furfuryl alcohol into ethyl levulinate
文献类型：期刊论文
| 作者 | Yuan, Haoran1,2,3,4; Li, Chengyu1,2; Shan, Rui1,2,3,4,5; Zhang, Jun1,2,3,4; Chen, Yong1,2,3,4 |
| 刊名 | REACTION CHEMISTRY & ENGINEERING
 |
| 出版日期 | 2023-07-11 |
| 页码 | 8 |
| ISSN号 | 2058-9883 |
| DOI | 10.1039/d3re00311f |
| 通讯作者 | Zhang, Jun(zhangjun@ms.giec.ac.cn) |
| 英文摘要 | A series of antibiotic residue derived solid acids were developed for the selective transformation of bio-based furfuryl alcohol into ethyl levulinate. KOH modification and chlorosulfonic acid decoration of gentamicin residue derived carbon materials played a crucial role in ethyl levulinate production. Various characterization methods were employed for unveiling the structural information regarding porous characteristics and functional groups, such as FT-IR, N-2 adsorption-desorption, SEM, etc. The yields of 2-(ethoxymethyl)furan and ethyl levulinate were particularly associated with the acid density of gentamicin residue derived solid acids. Gratifyingly, a maximum ethyl levulinate yield of 84.5% was achieved at 160 & DEG;C after 1.5 h. The recovery and reutilization of the catalyst in successive reactions demonstrated that gentamicin residue derived solid acids maintained good activity and stability even after four cycles. The present research thus highlights a novel direction for high-value utilization of antibiotic residues as well as the synthesis of platform chemicals over organic waste derived catalytic materials. |
| WOS关键词 | CATALYTIC PERFORMANCE ; SULFONIC-ACID ; CONVERSION ; PYROLYSIS |
| 资助项目 | National Key Ramp;D Program of China[2019YFC1906605] ; National Natural Science Foundation of China[51976222] ; National Natural Science Foundation of China[52276219] ; Guangdong Basic and Applied Basic Research Foundation[2021B1515020068] ; Project of Science and Technology of Guangzhou[202201010328] ; Yangfan Plan Innovation Team of Guangdong Province[2017YT05N093] ; Youth Innovation Promotion Association CAS[2023367] |
| WOS研究方向 | Chemistry ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:001034820100001 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 资助机构 | National Key Ramp;D Program of China ; National Natural Science Foundation of China ; Guangdong Basic and Applied Basic Research Foundation ; Project of Science and Technology of Guangzhou ; Yangfan Plan Innovation Team of Guangdong Province ; Youth Innovation Promotion Association CAS |
| 源URL | [http://ir.giec.ac.cn/handle/344007/39352]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Zhang, Jun |
| 作者单位 | 1.Univ Sci & Technol China, Sch Energy Sci & Engn, Guangzhou 510640, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 3.CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 4.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 5.Shuye Environm Technol Co Ltd, Shantou 515800, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yuan, Haoran,Li, Chengyu,Shan, Rui,et al. Antibiotic residue derived solid acids for ethanolysis of furfuryl alcohol into ethyl levulinate[J]. REACTION CHEMISTRY & ENGINEERING,2023:8. |
| APA | Yuan, Haoran,Li, Chengyu,Shan, Rui,Zhang, Jun,&Chen, Yong.(2023).Antibiotic residue derived solid acids for ethanolysis of furfuryl alcohol into ethyl levulinate.REACTION CHEMISTRY & ENGINEERING,8. |
| MLA | Yuan, Haoran,et al."Antibiotic residue derived solid acids for ethanolysis of furfuryl alcohol into ethyl levulinate".REACTION CHEMISTRY & ENGINEERING (2023):8. |
入库方式： OAI收割
来源：广州能源研究所
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