Facile synthesis of Pd@MOF catalyst and its application for highly selective catalytic reduction of biomass-derived compounds towards tunable products
文献类型：期刊论文
| 作者 | Wei, Xiu-Zhi1,3; Wang, Haiyong3; Liu, Jianguo2; Ma, Longlong1,2 |
| 刊名 | INORGANIC CHEMISTRY COMMUNICATIONS
 |
| 出版日期 | 2023-08-01 |
| 卷号 | 154页码:10 |
| 关键词 | MOF Vanillin Hydrodeoxygenation Biomass-derived compounds Time-tuning |
| ISSN号 | 1387-7003 |
| DOI | 10.1016/j.inoche.2023.110956 |
| 通讯作者 | Wang, Haiyong() ; Liu, Jianguo(liujg@seu.edu.cn) ; Ma, Longlong(mall@seu.edu.cn) |
| 英文摘要 | High selective reduction of biomass-derived compounds is still challenging especially under mild reaction con-ditions using heterogeneous catalysis. Here, we reported a one-step synthesis method that successfully prepared highly dispersed Pd species immobilized on NH2-MIL-125 (Ti) frameworks which were named Pd@MOF and used as a highly efficient hydrodeoxygenation catalyst for the reduction of vanillin to 2-methoxy-4-methyl phenol in excellent yield with an atm of H2 pressure at room temperature. Pd(PPh3)4 was dispersed in a sol-vent containing the MOFs precursors. Among them, the PPh3 ligand could be oxidized to remove and Pd particles in situ doped in MOFs framework during the solvothermal process. Compare to immersed-Pd/MOF and Pd-MOF, Pd@MOF has higher catalytic efficiency because the smaller Pd particles encapsulated in MOFs inhibit Pd over oxidation. Moreover, the different reduction products could be obtained selectively by tuning reaction time, and the catalyst realized to catalyze the highly effective transformation of a variety of biomass-derived compounds. |
| WOS关键词 | METAL-ORGANIC FRAMEWORK ; AEROBIC PHOTOCATALYTIC OXIDATION ; PALLADIUM ; HYDROGENATION ; CARBON ; HYDRODEOXYGENATION ; ALCOHOLS ; KETONES ; AMINES |
| 资助项目 | National Natural Science Foundation of China[52236010] ; National Natural Science Foundation of China[51976225] ; Fundamental Research Funds for the Central Universities[2242022R10058] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:001027533800001 |
| 出版者 | ELSEVIER |
| 资助机构 | National Natural Science Foundation of China ; Fundamental Research Funds for the Central Universities |
| 源URL | [http://ir.giec.ac.cn/handle/344007/39419]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Wang, Haiyong; Liu, Jianguo; Ma, Longlong |
| 作者单位 | 1.Univ Sci & Technol China, Dept Thermal Sci & Energy Engn, Hefei 230026, Peoples R China 2.Southeast Univ, Sch Energy & Environm, Key Lab Energy Thermal Convers & Control, Minist Educ, Nanjing 210096, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wei, Xiu-Zhi,Wang, Haiyong,Liu, Jianguo,et al. Facile synthesis of Pd@MOF catalyst and its application for highly selective catalytic reduction of biomass-derived compounds towards tunable products[J]. INORGANIC CHEMISTRY COMMUNICATIONS,2023,154:10. |
| APA | Wei, Xiu-Zhi,Wang, Haiyong,Liu, Jianguo,&Ma, Longlong.(2023).Facile synthesis of Pd@MOF catalyst and its application for highly selective catalytic reduction of biomass-derived compounds towards tunable products.INORGANIC CHEMISTRY COMMUNICATIONS,154,10. |
| MLA | Wei, Xiu-Zhi,et al."Facile synthesis of Pd@MOF catalyst and its application for highly selective catalytic reduction of biomass-derived compounds towards tunable products".INORGANIC CHEMISTRY COMMUNICATIONS 154(2023):10. |
入库方式： OAI收割
来源：广州能源研究所
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