Competitive adsorption of alcohols over heteroatom zeolites hinders the catalytic conversion of sugar
文献类型：期刊论文
| 作者 | Sun, Pengyao1,2,3,4; Wang, Haiyong1,2,3; Huang, Jiaxin1,2,3; Ling, Wenmeng1,2,3; Liao, Yuhe1,2,3; Wang, Chenguang1,2,3,4 |
| 刊名 | APPLIED CATALYSIS A-GENERAL
 |
| 出版日期 | 2023-07-25 |
| 卷号 | 662页码:9 |
| 关键词 | ATR-IR Heterogeneous catalysis Zeolite Solvent Glucose Lewis acid |
| ISSN号 | 0926-860X |
| DOI | 10.1016/j.apcata.2023.119258 |
| 通讯作者 | Wang, Chenguang(wangcg@ms.giec.ac.cn) |
| 英文摘要 | In the catalysis of glucose from bulk methanol to Lewis acid centers via zeolite pores, MES-ATR-IR and PSD detected competitive adsorption driven by hydrogen bonding ascribed to the hydroxyl of the solvent, substrate, and interface. The phase-resolved spectra show a change from methanol-to glucose-silicon hydroxyl bonds, which slows the rate of Lewis acid center carbonyl activation. Moreover, increased silicon hydroxyl binding to glucose results in lower acidity of metal centers in the process. It almost eliminates the variations in reactivity caused by metal identity. In contrast, the absence of hydroxyl at the solvent, substrate, or interface prevents competitive adsorption and brings out the acidity of different metal centers, with Sn > In > Hf > Ti > Zr being the order of binding ability to the carbonyl. This study contributes to the development of zeotype metal center local environments for substrate and solvent matching in various reaction networks. |
| WOS关键词 | TRANSFER HYDROGENATION ; LACTIC-ACID ; ACTIVE CATALYSTS ; BETA ZEOLITES ; SPECTROSCOPY ; SITES |
| 资助项目 | National Natural Science Foundation of China[52276220] ; Key Technologies Ramp;D Program of Guangdong Province[2020B1111570001] |
| WOS研究方向 | Chemistry ; Environmental Sciences & Ecology |
| 语种 | 英语 |
| WOS记录号 | WOS:001021103500001 |
| 出版者 | ELSEVIER |
| 资助机构 | National Natural Science Foundation of China ; Key Technologies Ramp;D Program of Guangdong Province |
| 源URL | [http://ir.giec.ac.cn/handle/344007/39478]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Wang, Chenguang |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, 2,Nengyuan Rd, Guangzhou 510640, Peoples R China 2.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou, Peoples R China 3.Chinese Acad Sci, Key Lab Renewable Energy, Beijing, Peoples R China 4.Univ Chinese Acad Sci, Beijing 101408, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun, Pengyao,Wang, Haiyong,Huang, Jiaxin,et al. Competitive adsorption of alcohols over heteroatom zeolites hinders the catalytic conversion of sugar[J]. APPLIED CATALYSIS A-GENERAL,2023,662:9. |
| APA | Sun, Pengyao,Wang, Haiyong,Huang, Jiaxin,Ling, Wenmeng,Liao, Yuhe,&Wang, Chenguang.(2023).Competitive adsorption of alcohols over heteroatom zeolites hinders the catalytic conversion of sugar.APPLIED CATALYSIS A-GENERAL,662,9. |
| MLA | Sun, Pengyao,et al."Competitive adsorption of alcohols over heteroatom zeolites hinders the catalytic conversion of sugar".APPLIED CATALYSIS A-GENERAL 662(2023):9. |
入库方式： OAI收割
来源：广州能源研究所
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