Green and efficient synthesis of primary amine from nitrile catalyzed by Pd-Ni oxide nanocluster
文献类型：期刊论文
| 作者 | Lu, Qiqi1,3; Wei, Xiu-Zhi4; Wang, Haiyong1,3; Zhang, Qi2; Zhang, Xinghua2; Chen, Lungang2; Liu, Jianguo2; Ma, Longlong2 |
| 刊名 | CHEMICAL ENGINEERING SCIENCE
 |
| 出版日期 | 2023-09-05 |
| 卷号 | 279页码:9 |
| 关键词 | Nitrile Primary amine Selective hydrogenation Bimetallic nanoclusters S-1 zeolite |
| ISSN号 | 0009-2509 |
| DOI | 10.1016/j.ces.2023.118929 |
| 通讯作者 | Liu, Jianguo(liujg@seu.edu.cn) ; Ma, Longlong(mall@seu.edu.cn) |
| 英文摘要 | The selective hydrogenation of nitrile represents an atom-economical and reliable method to synthesize primary amine, a privileged compound in chemistry, biology, and medicine. However, this approach often displays severe selectivity issues, and additives or reducing agents are generally required to solve this problem. In this work, we aim to synthesize primary amine on a green catalytic system and probe into the catalytic mechanism of Pd-Ni interaction using benzonitrile (BN) as a model compound. The nitrile hydrogenation reaction was catalyzed by bimetallic Pd-Ni oxide nanospecies confined in Silicalite-1 (S-1) zeolite using H2 as hydrogen donor without any additive which was environmentally friendly and economic. A 92% yield of benzylamine (BA) was achieved on the Pd0.6Ni@S-1 catalyst with a turnover number (TON) of 1667, and such BA yield was still maintained in upscaling experiment. Detailed characterizations shed light on the mechanism of the extraordinary performance of Pd-Ni oxide nanospecies on base-free nitrile hydrogenation. |
| WOS关键词 | SELECTIVE HYDROGENATION ; AMMONIA BORANE ; CARBON-DIOXIDE ; NANOPARTICLES ; ZEOLITE ; CO ; AMINATION ; GRAPHENE ; CLUSTERS ; ALLOY |
| 资助项目 | National Natural Science Foundation of China[51976225] ; National Natural Science Foundation of China[52006225] ; National Natural Science Foundation of China[2242022R10058] ; Funda- mental Research Funds for the Central Universities ; [52236010] |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:001053950400001 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 资助机构 | National Natural Science Foundation of China ; Funda- mental Research Funds for the Central Universities |
| 源URL | [http://ir.giec.ac.cn/handle/344007/39604]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Liu, Jianguo; Ma, Longlong |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangdong Prov Key Lab New & Renewable Energy Res, CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 2.Southeast Univ, Sch Energy & Environm, Key Lab Energy Thermal Convers & Control, Minist Educ, Nanjing 210096, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.Univ Sci & Technol China, Dept Engn Sci, Hefei 230026, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lu, Qiqi,Wei, Xiu-Zhi,Wang, Haiyong,et al. Green and efficient synthesis of primary amine from nitrile catalyzed by Pd-Ni oxide nanocluster[J]. CHEMICAL ENGINEERING SCIENCE,2023,279:9. |
| APA | Lu, Qiqi.,Wei, Xiu-Zhi.,Wang, Haiyong.,Zhang, Qi.,Zhang, Xinghua.,...&Ma, Longlong.(2023).Green and efficient synthesis of primary amine from nitrile catalyzed by Pd-Ni oxide nanocluster.CHEMICAL ENGINEERING SCIENCE,279,9. |
| MLA | Lu, Qiqi,et al."Green and efficient synthesis of primary amine from nitrile catalyzed by Pd-Ni oxide nanocluster".CHEMICAL ENGINEERING SCIENCE 279(2023):9. |
入库方式： OAI收割
来源：广州能源研究所
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