Production of 1,2-propanediol from fructose over a biochar-supported RuWCu catalyst
文献类型：期刊论文
| 作者 | Liu, Yong1; Chen, Lungang2; Chi, Dongfeng3; Wang, Chenguang1,4; Zhang, Xinghua2; Liu, Jianguo2; Zhang, Qi2; Ma, Longlong2 |
| 刊名 | SUSTAINABLE ENERGY & FUELS
 |
| 出版日期 | 2023-10-10 |
| 卷号 | 7期号:20页码:5156-5165 |
| ISSN号 | 2398-4902 |
| DOI | 10.1039/d3se00997a |
| 通讯作者 | Chen, Lungang(chenlg@seu.edu.cn) |
| 英文摘要 | The conversion of fructose, derived from biomass, into 1,2-propanediol (1,2-PDO) offers a promising approach for reducing the carbon footprint and achieving high atom economy. However, effective regulation of this transformation to minimize side reactions remains a challenge. In this study, a biochar supported RuWCu catalyst was developed demonstrating high activity of converting fructose to 1,2-propanediol with a favorable yield of 48.1% under optimized reaction conditions of 4 MPa H2, 210 degrees C, and 3 h. The calcination temperature and reduction temperature affected the states of Ru, W, and Cu, which in turn affected the metal-acid sites. Optimal results were obtained with a calcination temperature of 400 degrees C and a reduction temperature of 300 degrees C, resulting in a high yield of 1,2-PDO. The Ru0.5W36Cu7/biochar showed a good reuse potential with negligible activity loss after the fifth run. These findings contribute to the development of efficient catalysts for biomass conversion and highlight the potential of biochar-supported catalysts in sustainable chemical transformations. A pomelo peel-derived biochar supported RuWCu catalyst was synthesized for the production of 1,2-propanediol from fructose hydrodeoxygenation. |
| WOS关键词 | ETHYLENE-GLYCOL ; SELECTIVE HYDROGENOLYSIS ; GLYCEROL HYDROGENOLYSIS ; HIGHLY EFFICIENT ; TUNGSTEN CARBIDE ; CU/SIO2 CATALYST ; LEVULINIC ACID ; CONVERSION ; CELLULOSE ; GLUCOSE |
| 资助项目 | This study was supported by the National Natural Science Foundation of China (no. 52236010), the High Level Personnel Project of Jiangsu Province (no. JSSCBS20220085), the Talent Program of Jiangxi Province of China (grant no. jxsq2020102023), and the Fund |
| WOS研究方向 | Chemistry ; Energy & Fuels ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:001069326700001 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 资助机构 | This study was supported by the National Natural Science Foundation of China (no. 52236010), the High Level Personnel Project of Jiangsu Province (no. JSSCBS20220085), the Talent Program of Jiangxi Province of China (grant no. jxsq2020102023), and the Fund |
| 源URL | [http://ir.giec.ac.cn/handle/344007/39729]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Chen, Lungang |
| 作者单位 | 1.Nanchang Univ, Sch Resources & Environm, Key Lab Poyang Lake Environm & Resource Utilizat, Minist Educ, Nanchang 330031, Peoples R China 2.Southeast Univ, Key Lab Energy Thermal Convers & Control, Sch Energy & Environm, Minist Educ, Nanjing 210096, Peoples R China 3.Univ Sci & Technol China, Nano Sci & Technol Inst, Suzhou 215123, Peoples R China 4.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Yong,Chen, Lungang,Chi, Dongfeng,et al. Production of 1,2-propanediol from fructose over a biochar-supported RuWCu catalyst[J]. SUSTAINABLE ENERGY & FUELS,2023,7(20):5156-5165. |
| APA | Liu, Yong.,Chen, Lungang.,Chi, Dongfeng.,Wang, Chenguang.,Zhang, Xinghua.,...&Ma, Longlong.(2023).Production of 1,2-propanediol from fructose over a biochar-supported RuWCu catalyst.SUSTAINABLE ENERGY & FUELS,7(20),5156-5165. |
| MLA | Liu, Yong,et al."Production of 1,2-propanediol from fructose over a biochar-supported RuWCu catalyst".SUSTAINABLE ENERGY & FUELS 7.20(2023):5156-5165. |
入库方式： OAI收割
来源：广州能源研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。