Reconstituting Cu0/Cu+ synergy with heterostructured CeO2 enabling energy-efficient bipolar hydrogen generation
文献类型：期刊论文
| 作者 | Zhang, Xin2; Yu, Jing1; Shen, Hao-Jie2; Zhang, Lu2; Yang, Gai-Xiu3; Zhou, Xiao-Cheng1; Feng, Jiu-Ju2; Wang, Ai-Jun2 |
| 刊名 | CHEMICAL ENGINEERING JOURNAL
 |
| 出版日期 | 2023-11-01 |
| 卷号 | 475页码:10 |
| 关键词 | Heterostructures Synergistic effect Furfural oxidation reaction Hydrogen evolution reaction Bipolar hydrogen generation system |
| ISSN号 | 1385-8947 |
| DOI | 10.1016/j.cej.2023.146506 |
| 通讯作者 | Zhang, Lu(zhanglu@zjnu.edu.cn) ; Zhou, Xiao-Cheng(xczhou@njnu.edu.cn) ; Wang, Ai-Jun(ajwang@zjnu.edu.cn) |
| 英文摘要 | The establishment of electrocatalytic hydrogen (H2) production system with low energy consumption is of great significance for sustainable development. Herein, a groundbreaking achievement is presented by development of a bifunctional electrocatalyst (CeO2@Cu NRAs) on Cu foam, enabling simultaneously efficient catalysis of both hydrogen evolution reaction (HER,-0.18 VRHE at 10 mA cm-2) and furfural oxidation reaction (FFOR, 0.10 VRHE at 10 mA cm-2). The synergistic effect between Cu0 and Cu+ is investigated by density functional theory calculation, as well as the role of the heterostructured CeO2 played. Accordingly, subtle integration of such two half-reactions, the catalyst-assembled hydrogen system only requires an electrical input of 1.02 kWh per m3 of H2, which is one fifth of the energy consumed by conventional water electrolysis (5 kWh per m3 H2), signifying a compelling strategy for reducing energy consumption and improving the overall efficiency for hydrogen production. |
| WOS关键词 | EVOLUTION ; CU ; PERFORMANCE |
| 资助项目 | National Natural Science Foundation of China[21805245] ; National Natural Science Foundation of China[12202209] ; Natural Science Foundation of Jiangsu Province[BK20220379] ; Natural Science Foundation of Jiangsu Higher Education Institutions of China[21KJB150028] ; Shenzhen Science and Technology Program[JCYJ20200109150210400] |
| WOS研究方向 | Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:001096532800001 |
| 出版者 | ELSEVIER SCIENCE SA |
| 资助机构 | National Natural Science Foundation of China ; Natural Science Foundation of Jiangsu Province ; Natural Science Foundation of Jiangsu Higher Education Institutions of China ; Shenzhen Science and Technology Program |
| 源URL | [http://ir.giec.ac.cn/handle/344007/40102]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Zhang, Lu; Zhou, Xiao-Cheng; Wang, Ai-Jun |
| 作者单位 | 1.Nanjing Normal Univ, Jiangsu Collaborat Innovat Ctr Biomed Funct Mat, Sch Chem & Mat Sci, Jiangsu Key Lab New Power Batteries, Nanjing 210023, Jiangsu, Peoples R China 2.Zhejiang Normal Univ, Coll Chem & Mat Sci, Coll Geog & Environm Sci, Key Lab Minist Educ Adv Catalysis Mat, Jinhua 321004, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Xin,Yu, Jing,Shen, Hao-Jie,et al. Reconstituting Cu0/Cu+ synergy with heterostructured CeO2 enabling energy-efficient bipolar hydrogen generation[J]. CHEMICAL ENGINEERING JOURNAL,2023,475:10. |
| APA | Zhang, Xin.,Yu, Jing.,Shen, Hao-Jie.,Zhang, Lu.,Yang, Gai-Xiu.,...&Wang, Ai-Jun.(2023).Reconstituting Cu0/Cu+ synergy with heterostructured CeO2 enabling energy-efficient bipolar hydrogen generation.CHEMICAL ENGINEERING JOURNAL,475,10. |
| MLA | Zhang, Xin,et al."Reconstituting Cu0/Cu+ synergy with heterostructured CeO2 enabling energy-efficient bipolar hydrogen generation".CHEMICAL ENGINEERING JOURNAL 475(2023):10. |
入库方式： OAI收割
来源：广州能源研究所
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