Fully bio-based epoxy resins from lignin and epoxidized soybean oil: Rigid-flexible, tunable properties and high lignin content
文献类型：期刊论文
| 作者 | Zhen, Xiang1,2,3; Cui, Xuelu2; Al-Haimi, Akram Ali Nasser Mansoor3,4; Wang, Xiaobing2; Liang, Huijun5; Xu, Zhongbin3; Wang, Zhongming3 |
| 刊名 | INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
 |
| 出版日期 | 2024 |
| 卷号 | 254页码:11 |
| 关键词 | Lignin Epoxidized soybean oil Thermosets |
| ISSN号 | 0141-8130 |
| DOI | 10.1016/j.ijbiomac.2023.127760 |
| 通讯作者 | Zhen, Xiang(15903062113@163.com) |
| 英文摘要 | The application of epoxidized soybean oil (ESO) in thermosetting polymers is impeded by its unsatisfactory thermomechanical properties. Here, in order to address the limitation, technical lignin was modified by tung oil anhydride and then used as the hardener to compensate for the inherent flexibility defects of ESO thermosets (TLs). As the lignin content increased, a notable improvement in the activation energy of TLs was observed, attributed to the restraining effect of lignin's rigid structure on segmental relaxation. Concurrently, the tensile strength of TLs increased from 2.8 MPa to 34.0 MPa, concomitant with a decrease in elongation at break from 32.9 % to 8.0 %. Comparative analysis with TL-0 (devoid of lignin) demonstrated substantial enhancements in glass transition temperature, shape fixation ratio, and shape recovery ratio for TL-50 (comprising 50 wt% of lignin), elevating from 16.9 degrees C, 89.1 %, and 89.5 % to 118.6 degrees C, 94.0 %, and 99.3 %, respectively. These results unequivocally highlight the favorable dynamic mechanical and shape memory properties conferred upon TLs by lignin addition. While the introduction of lignin adversely affected thermal stability, a notable improvement in char yield (800 degrees C) was observed. Collectively, these findings underscore the potential of technical lignin as a promising bio-based curing agent for ESO. |
| WOS关键词 | HIGH-PERFORMANCE ; THERMOSETS ; ANHYDRIDE ; ACID |
| 资助项目 | National Key Research and Devel-opment Program of China[2022YFE0207100] ; Natural Science Foundation of Henan Province[222300420511] |
| WOS研究方向 | Biochemistry & Molecular Biology ; Chemistry ; Polymer Science |
| 语种 | 英语 |
| WOS记录号 | WOS:001110243400001 |
| 出版者 | ELSEVIER |
| 资助机构 | National Key Research and Devel-opment Program of China ; Natural Science Foundation of Henan Province |
| 源URL | [http://ir.giec.ac.cn/handle/344007/40254]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Zhen, Xiang |
| 作者单位 | 1.46 Jianshe Rd, Xinxiang 453007, Peoples R China 2.Henan Normal Univ, Sch Chem & Chem Engn, Xinxiang 453007, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 4.Univ Sci & Technol China, Hefei 230026, Peoples R China 5.Xinxiang Univ, Sch Chem & Mat Engn, Xinxiang 453003, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhen, Xiang,Cui, Xuelu,Al-Haimi, Akram Ali Nasser Mansoor,et al. Fully bio-based epoxy resins from lignin and epoxidized soybean oil: Rigid-flexible, tunable properties and high lignin content[J]. INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES,2024,254:11. |
| APA | Zhen, Xiang.,Cui, Xuelu.,Al-Haimi, Akram Ali Nasser Mansoor.,Wang, Xiaobing.,Liang, Huijun.,...&Wang, Zhongming.(2024).Fully bio-based epoxy resins from lignin and epoxidized soybean oil: Rigid-flexible, tunable properties and high lignin content.INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES,254,11. |
| MLA | Zhen, Xiang,et al."Fully bio-based epoxy resins from lignin and epoxidized soybean oil: Rigid-flexible, tunable properties and high lignin content".INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES 254(2024):11. |
入库方式： OAI收割
来源：广州能源研究所
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