Study of efficient catalytic electrode for hydrogen evolution reaction from seawater based on low tortuosity corn straw cellulose biochar/Mo2C with porous channels
文献类型：期刊论文
| 作者 | Li, Hongru2; Zhen, Feng3,4; Qian, Xin2; Yang, Jiaxun1,2; Yu, Hailong1; Wang, Qiyu1; Zhang, Lingling2; Wang, Yuxin2; Qu, Bin2,5 |
| 刊名 | INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
 |
| 出版日期 | 2024 |
| 卷号 | 254页码:10 |
| 关键词 | Biochar Tortuosity Catalyst |
| ISSN号 | 0141-8130 |
| DOI | 10.1016/j.ijbiomac.2023.127993 |
| 通讯作者 | Qu, Bin(qubin@neau.edu.cn) |
| 英文摘要 | Porosity and channel structure has important effects on the performance of hydrogen evolution reaction (HER) of nanostructured electrocatalysts in acid solution and seawater. Mesopore usually helps to enhance the reaction kinetics and mass transfer, while the macroporous channel structure also affects the electrocatalyst. Traditional graphene materials do not have such structure. Therefore, this paper designs a method to synthesize Mo2C composite nanomaterial in situ on corn straw biochar, inspires by the natural channel structure of conducting water, salt and organic matter in plants. Characteristic characterization shows that the material also has a large number of mesoporous and vertical distribution of large porous channel structure, through the decrease of tortuosity and porosity, ensure the catalyst surface electrolyte transport and hydrogen timely escape, alleviate the process of metal ion precipitation blocking pore channel, so as to improve the rate of hydrogen evolution reaction. The results shows that the overpotential of the catalyst was 48 mV and 251 mV under 10 mA cm-2 acidic electrolyte and simulated seawater electrolyte, respectively. This method provides new ideas for the design of efficient electrocatalysts for seawater decomposition, then the HER performance in alkaline and neutral environments needs to be further explored. |
| WOS关键词 | ELECTROCATALYSTS ; NANOSHEETS ; NANOPARTICLES ; CONSTRUCTION ; CARBIDE ; MO2C |
| 资助项目 | National Natural Science Foundation of China[22209022] ; Key Research and Development Program of Guangzhou[2023B03J1229] |
| WOS研究方向 | Biochemistry & Molecular Biology ; Chemistry ; Polymer Science |
| 语种 | 英语 |
| WOS记录号 | WOS:001111811700001 |
| 出版者 | ELSEVIER |
| 资助机构 | National Natural Science Foundation of China ; Key Research and Development Program of Guangzhou |
| 源URL | [http://ir.giec.ac.cn/handle/344007/40320]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Qu, Bin |
| 作者单位 | 1.Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100190, Peoples R China 2.Northeast Agr Univ, Coll Art & Sci, Harbin 150030, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 4.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 5.600 Changjiang Rd, Harbin 150030, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Hongru,Zhen, Feng,Qian, Xin,et al. Study of efficient catalytic electrode for hydrogen evolution reaction from seawater based on low tortuosity corn straw cellulose biochar/Mo2C with porous channels[J]. INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES,2024,254:10. |
| APA | Li, Hongru.,Zhen, Feng.,Qian, Xin.,Yang, Jiaxun.,Yu, Hailong.,...&Qu, Bin.(2024).Study of efficient catalytic electrode for hydrogen evolution reaction from seawater based on low tortuosity corn straw cellulose biochar/Mo2C with porous channels.INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES,254,10. |
| MLA | Li, Hongru,et al."Study of efficient catalytic electrode for hydrogen evolution reaction from seawater based on low tortuosity corn straw cellulose biochar/Mo2C with porous channels".INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES 254(2024):10. |
入库方式： OAI收割
来源：广州能源研究所
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