Preparation of Ar-P-N-structured flame retardant via Kabachnik-Fields reaction for fire safety and mechanical reinforcement of polyurethane
文献类型：期刊论文
| 作者 | Choi, Jinkyu1,2; Min, Kyung Hoon1; Kim, Byeong Seok1; Baeck, Sung-Hyeon1; Shim, Sang Eun1; Qian, Yingjie1,2 |
| 刊名 | PROGRESS IN ORGANIC COATINGS
 |
| 出版日期 | 2024 |
| 卷号 | 186页码:15 |
| 关键词 | Polyurethane Organophosphorus flame retardant Flame retardancy Mechanical properties pi-pi interaction Castor oil |
| ISSN号 | 0300-9440 |
| DOI | 10.1016/j.porgcoat.2023.108081 |
| 通讯作者 | Shim, Sang Eun(seshim@inha.ac.kr) ; Qian, Yingjie(qianyj@ms.giec.ac.cn) |
| 英文摘要 | Fire safety of polyurethanes (PUs) has limited their further practical applications. To address this problem, we designed novel phosphorus-based flame retardants (P-FR) by incorporating aryl (Ar) groups via Kabachnik-Fields reaction, realizing pi-pi interaction-reinforced Ar2 and Ar5. Total heat release and peak heat release rate of PU/Ar5, whose flame-retardancy-index of 5.02 due to reduced combustion time, decreased 23.24 and 9.23 %, respectively, compared with neat PU. Moreover, UL94 rating for PU/Ar5 was improved from V-2 to V-0. These results demonstrate that Ar5 effectively generate a barrier effect that blocks oxygen, fuel, and heat. Sluggish mobility and phase transition are responsible for such enhancement due to a delay effect with the existence of pi-pi interactions and steric hindrance. Encouragingly, tensile strength and toughness of PU/Ar5 were greatly improved by 1345.8 and 670.3 %, respectively, compared with neat PU. We believe that this study could provide a promising method for introducing specific function to flame retardants to enhance fire safety and mechanical properties of composites. |
| WOS关键词 | PHOSPHORUS ; NITROGEN ; POLYMERIZATION ; POLYPHOSPHATE ; SUPPRESSION ; NANOSHEETS ; BORON ; ACID ; CO |
| 资助项目 | National Research Foundation of Korea (NRF) - Korea government (MSIT)[2020R1A5A1019131] |
| WOS研究方向 | Chemistry ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:001124097300001 |
| 出版者 | ELSEVIER SCIENCE SA |
| 资助机构 | National Research Foundation of Korea (NRF) - Korea government (MSIT) |
| 源URL | [http://ir.giec.ac.cn/handle/344007/40445]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Shim, Sang Eun; Qian, Yingjie |
| 作者单位 | 1.Inha Univ, Educ & Res Ctr Smart Energy & Mat, Dept Chem & Chem Engn, Incheon 22212, South Korea 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China |
| 推荐引用方式 GB/T 7714 | Choi, Jinkyu,Min, Kyung Hoon,Kim, Byeong Seok,et al. Preparation of Ar-P-N-structured flame retardant via Kabachnik-Fields reaction for fire safety and mechanical reinforcement of polyurethane[J]. PROGRESS IN ORGANIC COATINGS,2024,186:15. |
| APA | Choi, Jinkyu,Min, Kyung Hoon,Kim, Byeong Seok,Baeck, Sung-Hyeon,Shim, Sang Eun,&Qian, Yingjie.(2024).Preparation of Ar-P-N-structured flame retardant via Kabachnik-Fields reaction for fire safety and mechanical reinforcement of polyurethane.PROGRESS IN ORGANIC COATINGS,186,15. |
| MLA | Choi, Jinkyu,et al."Preparation of Ar-P-N-structured flame retardant via Kabachnik-Fields reaction for fire safety and mechanical reinforcement of polyurethane".PROGRESS IN ORGANIC COATINGS 186(2024):15. |
入库方式： OAI收割
来源：广州能源研究所
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