Flexible and Heat-Resisting Lignin-Based Epoxy Resins by Hardwood Kraft Low-Molecular-Weight Lignin as a Sustainable Substitute for Bisphenol A
文献类型：期刊论文
| 作者 | Xue, Min1; Hu, Songnan1; Zhang, Shuo1; Ou, Jinfen1; Chen, Honglei2; Liao, Yuhe3; Yue, Fengxia1,2 |
| 刊名 | ACS SUSTAINABLE CHEMISTRY & ENGINEERING
 |
| 出版日期 | 2023-11-13 |
| 卷号 | 11期号:47页码:16774-16784 |
| 关键词 | low-molecular-weight lignin glycidyl ether epoxy resin syringaresinol stilbene epoxy value |
| ISSN号 | 2168-0485 |
| DOI | 10.1021/acssuschemeng.3c04898 |
| 通讯作者 | Yue, Fengxia(yuefx@scut.edu.cn) |
| 英文摘要 | Finding renewable substitutes for bisphenol A (BPA) for producing epoxy resin is of high practical significance. While the low cost and high yield of lignin make it a promising candidate, its high molecular weight, low reactivity, and high dispersity limit its applications. Here, we utilized a low-molecular-weight (low-Mw) lignin mainly consisting of syringaresinol and stilbenes with low dispersity and rich hydroxyl groups as a partial substitute for BPA to synthesize epoxy resins. The resulting lignin-based epoxy resins were designed under three different reaction conditions to yield lignin replacement amounts of 20, 40, and 60%. The epoxy resins with a 20% substitute amount exhibited the best properties with enhanced elongation (239%), tensile stress (144%), and thermal stability (48%) compared to the BPA-based epoxy resin. This study revealed that, besides the epoxy value, low-Mw lignin derivatives including syringaresinol, stilbenes, and aldoketones are essential in improving the elongation. Especially, the newly proposed possible open-loop mechanism of syringaresinol (beta-beta) indicates that the cross-linked network formed by the furan ring-opening after curing could further reinforce the epoxy resins' mechanical properties. It provides a new sustainable substitute for BPA to design flexible and heat-resistant lignin-based epoxy resins. |
| WOS关键词 | THERMOSETS ; MONOMERS |
| 资助项目 | Natural Science Foundation of Guangdong Province[2023A1515011972] ; Natural Science Foundation of Guangdong Province[KF202008] ; Foundation of the Key Laboratory of Pulp and Paper Science & Technology of the Ministry of Education of China |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:001142971400001 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | Natural Science Foundation of Guangdong Province ; Natural Science Foundation of Guangdong Province ; Foundation of the Key Laboratory of Pulp and Paper Science & Technology of the Ministry of Education of China |
| 源URL | [http://ir.giec.ac.cn/handle/344007/40659]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Yue, Fengxia |
| 作者单位 | 1.South China Univ Technol, Sch Light Ind & Engn, State Key Lab Pulp & Paper Engn, Guangzhou 510640, Peoples R China 2.Qilu Univ Technol, Shandong Acad Sci, Key Lab Pulp & Paper Sci & Technol, Minist Educ, Jinan 250353, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xue, Min,Hu, Songnan,Zhang, Shuo,et al. Flexible and Heat-Resisting Lignin-Based Epoxy Resins by Hardwood Kraft Low-Molecular-Weight Lignin as a Sustainable Substitute for Bisphenol A[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2023,11(47):16774-16784. |
| APA | Xue, Min.,Hu, Songnan.,Zhang, Shuo.,Ou, Jinfen.,Chen, Honglei.,...&Yue, Fengxia.(2023).Flexible and Heat-Resisting Lignin-Based Epoxy Resins by Hardwood Kraft Low-Molecular-Weight Lignin as a Sustainable Substitute for Bisphenol A.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,11(47),16774-16784. |
| MLA | Xue, Min,et al."Flexible and Heat-Resisting Lignin-Based Epoxy Resins by Hardwood Kraft Low-Molecular-Weight Lignin as a Sustainable Substitute for Bisphenol A".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 11.47(2023):16774-16784. |
入库方式： OAI收割
来源：广州能源研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。