Selective production of aromatics from catalytic fast pyrolysis of cassava residues over vanadium modified ZSM-5: Experimental and kinetic study
文献类型：期刊论文
| 作者 | Zhong, Shengliang1; Zhang, Jun1,2,3,4; Li, Chengyu1,2; Shan, Rui1,2,3,4; Yuan, Haoran1,2,3,4; Chen, Yong1,2,3,4 |
| 刊名 | JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS
 |
| 出版日期 | 2024 |
| 卷号 | 177页码:9 |
| 关键词 | Cassava residue Catalytic pyrolysis Kinetics Aromatics |
| ISSN号 | 0165-2370 |
| DOI | 10.1016/j.jaap.2023.106334 |
| 通讯作者 | Yuan, Haoran(yuanhr@ms.giec.ac.cn) |
| 英文摘要 | In the present study, vanadium modified ZSM-5 catalysts (denoted as xV/ZSM-5) were applied for the fast pyrolysis of cassava residues. Systematical structural characterizations were carried out to reveal the basic characteristics of as-prepared xV/ZSM-5. Remarkably, the incorporation of vanadium species endowed the catalysts with large amounts of Bronsted and Lewis acid sites, thus facilitating the formation of aromatics via catalytic cleavage, dehydration, decarbonylation, decarboxylation, cyclization, and aromatization. Among the asprepared xV/ZSM-5, 3V/ZSM-5 was found to be much more efficient in the fast pyrolysis of cassava residues into aromatics. The total yield of aromatics was up to 22.63 wt% at 750 degrees C with a heating rate of 10 degrees C/ms, and the corresponding apparent activation energy of 211.9 kJ/mol was attained. The recycling experiments demonstrated that the vanadium modified ZSM-5 catalysts presented good thermal stability and could be reused for several cycles. Furthermore, plausible reaction mechanism for the fast pyrolysis of cassava residues over vanadium modified ZSM-5 was discussed in depth. |
| WOS关键词 | RENEWABLE ENERGY ; CONVERSION ; H-ZSM-5 ; BIOMASS |
| 资助项目 | National Natural Science Foundation of China[52276219] ; National Natural Science Foundation of China[51976222] ; Guangdong Basic and Applied Basic Research Foundation[2021B1515020068] ; CAS Project for Young Scientists in Basic Research[YSBR-044] ; Project of Sci- ence and Technology of Guangzhou[202201010328] |
| WOS研究方向 | Chemistry ; Energy & Fuels ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:001153361200001 |
| 出版者 | ELSEVIER |
| 资助机构 | National Natural Science Foundation of China ; Guangdong Basic and Applied Basic Research Foundation ; CAS Project for Young Scientists in Basic Research ; Project of Sci- ence and Technology of Guangzhou |
| 源URL | [http://ir.giec.ac.cn/handle/344007/40807]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Yuan, Haoran |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 2.CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 3.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 4.Univ Sci & Technol China, Sch Energy Sci & Engn, Guangzhou 510640, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhong, Shengliang,Zhang, Jun,Li, Chengyu,et al. Selective production of aromatics from catalytic fast pyrolysis of cassava residues over vanadium modified ZSM-5: Experimental and kinetic study[J]. JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS,2024,177:9. |
| APA | Zhong, Shengliang,Zhang, Jun,Li, Chengyu,Shan, Rui,Yuan, Haoran,&Chen, Yong.(2024).Selective production of aromatics from catalytic fast pyrolysis of cassava residues over vanadium modified ZSM-5: Experimental and kinetic study.JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS,177,9. |
| MLA | Zhong, Shengliang,et al."Selective production of aromatics from catalytic fast pyrolysis of cassava residues over vanadium modified ZSM-5: Experimental and kinetic study".JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS 177(2024):9. |
入库方式： OAI收割
来源：广州能源研究所
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