Acid-Base Cascades in Zeotype Single Crystal for Sugar Conversion
文献类型：期刊论文
| 作者 | Sun, Pengyao1,6; Wang, Haiyong1; Wang, He2; Ling, Wenmeng1; Liu, Yong3,4; Zhou, Wenguang3,4; Liao, Yuhe1; Wang, Liang5; Lin, Yue2; Wang, Chenguang1,6 |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2024-02-05 |
| 页码 | 9 |
| 关键词 | Zeolites Carbohydrate conversion Solid acid Solid base Heterogeneous catalysis |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.202318750 |
| 通讯作者 | Wang, Chenguang(wangcg@ms.giec.ac.cn) |
| 英文摘要 | The chemically catalyzed production of fructose syrup from high concentrations of glucose is crucial for the food industry and biorefining. In this work, a single crystal catalyst was synthesized via protective desilication of zeolite while incorporating indium. Glucose was isomerized in methanol at concentrations as high as 33 wt % before being hydrolyzed with water. The final fructose production was 54.9 %, with 89.1 % selectivity and 93.3 % sugar recovery, the highest isomerization rate at the highest concentration ever reported. Indium was present in the single-crystal catalyst as oxide nanoparticles and boundary framework atoms, and it achieved intelligent cooperation in the production of fructose syrup in methanol by catalyzing isomerization and selective glycosidation, minimizing degradation due to fructose accumulation and eliminating side reactions. This study contributed to the advancement of the industrial practice of chemically catalyzed glucose isomerization. A single-crystal indium-containing zeolite catalyst with both Lewis acid and base sites intelligently participated in the isomerization of very high concentrations of glucose (33 %) to fructose in methanol, yielding 54.9 % fructose and recovering 93.9 % total sugar following tandem hydrolysis.+ image |
| WOS关键词 | FRUCTOSE CORN SYRUP ; GLUCOSE ISOMERIZATION ; ENERGY-INTAKE ; CATALYSTS ; ZEOLITES ; BIOMASS ; SITES |
| 资助项目 | National Natural Science Foundation of China ; Key Technologies R&D Program of Guangdong Province[2020B1111570001] ; Youth Innovation Promotion Association, CAS ; [52276220] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:001156464600001 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | National Natural Science Foundation of China ; Key Technologies R&D Program of Guangdong Province ; Youth Innovation Promotion Association, CAS |
| 源URL | [http://ir.giec.ac.cn/handle/344007/40861]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Wang, Chenguang |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangdong Prov Key Lab New & Renewable Energy Res, 2 Nengyuan Rd, Guangzhou 510640, Peoples R China 2.Univ Sci & Technol China, Hefei Natl Res Ctr Phys Sci Microscale, Dept Chem, Hefei 230026, Anhui, Peoples R China 3.Nanchang Univ, Sch Resources & Environm, Minist Educ, Nanchang 330031, Peoples R China 4.Nanchang Univ, Key Lab Poyang Lake Environm & Resource Utilizat, Minist Educ, Nanchang 330031, Peoples R China 5.Zhejiang Univ, Coll Chem & Biol Engn, Key Lab Biomass Chem Engn, Minist Educ, Hangzhou 310058, Peoples R China 6.Univ Chinese Acad Sci, Beijing 100046, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun, Pengyao,Wang, Haiyong,Wang, He,et al. Acid-Base Cascades in Zeotype Single Crystal for Sugar Conversion[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2024:9. |
| APA | Sun, Pengyao.,Wang, Haiyong.,Wang, He.,Ling, Wenmeng.,Liu, Yong.,...&Wang, Chenguang.(2024).Acid-Base Cascades in Zeotype Single Crystal for Sugar Conversion.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,9. |
| MLA | Sun, Pengyao,et al."Acid-Base Cascades in Zeotype Single Crystal for Sugar Conversion".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2024):9. |
入库方式： OAI收割
来源：广州能源研究所
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