Co-pyrolysis mechanism of waste vehicle seats derived artificial leather and foam
文献类型：期刊论文
| 作者 | Zhang, Jun1,2,3,4; Zhong, Shengliang1; Li, Chengyu1,2; Shan, Rui1,2,3,4; Yuan, Haoran1,2,3,4; Chen, Yong1,2,3,4 |
| 刊名 | JOURNAL OF CLEANER PRODUCTION
 |
| 出版日期 | 2024 |
| 卷号 | 434页码:9 |
| 关键词 | Waste vehicle seat Artificial leather PVC Polyurethane Co-pyrolysis |
| ISSN号 | 0959-6526 |
| DOI | 10.1016/j.jclepro.2023.140436 |
| 通讯作者 | Yuan, Haoran(yuanhr@ms.giec.ac.cn) |
| 英文摘要 | Co-pyrolysis is an important means to realize the clean disposal of organic wastes and generate some value-added chemicals. In the present study, the co-pyrolysis behavior of polyvinyl chloride (PVC) artificial leather (LE) and polyurethane foam (PU), the main components of waste vehicle seats, was systematically investigated to uncover the existing synergistic interaction effects. The pyrolysis experiments and kinetic analysis were carried out using TG/MS and Py-GC/MS, wherein the key parameters such as temperature and LE-to-PU mass ratio were examined. The co-pyrolysis of LE and PU at 650 degrees C remarkably accelerated the formation of aromatic compounds such as styrene. The relative content of aromatics from co-pyrolysis achieved 43.8%, which was much higher than that of 20.4% and 5.2% in the case of individual pyrolysis. The kinetic results further verified that the synergistic effect of LE and PU greatly lowered the reaction energy barriers of key steps in the co-pyrolysis, especially for the cases of LE-to-PU mass ratios of 3:2 and 2:3. The competing reactions such as intermolecular cross-linking of conjugated polyolefin intermediates and C-C cleavage, as well as the thermal conversion of methyl diphenyl diisocyanate in PU, favored the selective production of aromatics. In addition, the plausible pathways and synergistic mechanisms for the co-pyrolysis of LE and PU were discussed in detail. The present research significantly contributes to the selective upgrading of PVC artificial leather and polyurethane foam into highquality pyrolysis oils rich in aromatics, thus achieving the clean disposal and resource utilization of waste vehicle seats. |
| WOS关键词 | POLYURETHANE FOAM ; THERMAL-DECOMPOSITION ; VACUUM PYROLYSIS ; PVC ; LIFE ; END ; PRETREATMENT ; KINETICS ; PLASTICS ; ENERGY |
| 资助项目 | National Key R & D Program of China[2022YFC3902604] ; National Natural Science Foundation of China[52276219] ; Guangdong Basic and Applied Basic Research Foundation[2021B1515020068] ; CAS Project for Young Scientists in Basic Research[YSBR-044] ; Youth Innovation Promotion Association CAS[2023367] |
| WOS研究方向 | Science & Technology - Other Topics ; Engineering ; Environmental Sciences & Ecology |
| 语种 | 英语 |
| WOS记录号 | WOS:001166178600001 |
| 出版者 | ELSEVIER SCI LTD |
| 资助机构 | National Key R & D Program of China ; National Natural Science Foundation of China ; Guangdong Basic and Applied Basic Research Foundation ; CAS Project for Young Scientists in Basic Research ; Youth Innovation Promotion Association CAS |
| 源URL | [http://ir.giec.ac.cn/handle/344007/41011]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Yuan, Haoran |
| 作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 2.Univ Sci & Technol China, Sch Energy Sci & Engn, Guangzhou 510640, Peoples R China 3.CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 4.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Jun,Zhong, Shengliang,Li, Chengyu,et al. Co-pyrolysis mechanism of waste vehicle seats derived artificial leather and foam[J]. JOURNAL OF CLEANER PRODUCTION,2024,434:9. |
| APA | Zhang, Jun,Zhong, Shengliang,Li, Chengyu,Shan, Rui,Yuan, Haoran,&Chen, Yong.(2024).Co-pyrolysis mechanism of waste vehicle seats derived artificial leather and foam.JOURNAL OF CLEANER PRODUCTION,434,9. |
| MLA | Zhang, Jun,et al."Co-pyrolysis mechanism of waste vehicle seats derived artificial leather and foam".JOURNAL OF CLEANER PRODUCTION 434(2024):9. |
入库方式： OAI收割
来源：广州能源研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。