Direct Hydrogenation of Furfural to 2-Methyltetrahydrofuran over an Efficient Cu-Pd/HY Bimetallic Catalyst
文献类型：期刊论文
| 作者 | Yang, Bin1,2; Chen, Peili2; Zhu, Tianhan2; Dong, Guilin2; Wang, Haiyong2; Liao, Yuhe2; Zhang, Xinghua3; Ma, Longlong1,3 |
| 刊名 | ENERGY & FUELS
 |
| 出版日期 | 2024-03-11 |
| 卷号 | 38期号:6页码:5303-5313 |
| ISSN号 | 0887-0624 |
| DOI | 10.1021/acs.energyfuels.4c00043 |
| 通讯作者 | Wang, Haiyong(wanghy@ms.giec.ac.cn) ; Ma, Longlong(mall@seu.edu.cn) |
| 英文摘要 | The direct one-pot conversion of furfural to 2-methyltetrahydrofuran (2-MTHF) was investigated in liquid phases using H-2 as a hydrogen source over a bimetallic Cu-Pd/HY catalyst. This catalyst showed excellent catalytic reactivity toward the formation of 2-MTHF with a yield of 83.1% under optimized reaction conditions. By adjusting the Cu/Pd ratio in the catalyst, the desired product could be obtained selectively. This was due to (1) selective catalysis of Cu toward C=O bonds in furfural, (2) excellent hydrogenation ability of Pd, and (3) the synergistic effects between Cu, Pd, and the acidic sites of the support HY. The influences of other parameters on conversion and selectivity were also investigated. Mechanism studies revealed that reactions mainly perform through the hydrogenation of furfural to furfuryl alcohol and then hydrodeoxygenation to 2-methylfuran followed by furan ring hydrogenation to 2-MTHF. Finally, after five recycling runs, this catalyst still displayed high catalytic behavior and stability, which provided a certain foundation for future research of furfural catalytic hydrogenation to 2-MTHF. |
| WOS关键词 | CONVERSION ; PLATFORM ; CHEMICALS ; ALCOHOL ; BIOMASS ; CO |
| 资助项目 | National Natural Science Foundation of China[52276220] ; National Natural Science Foundation of China[52176213] ; National Natural Science Foundation of China ; Youth Innovation Promotion Association, CAS |
| WOS研究方向 | Energy & Fuels ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:001184709800001 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | National Natural Science Foundation of China ; National Natural Science Foundation of China ; Youth Innovation Promotion Association, CAS |
| 源URL | [http://ir.giec.ac.cn/handle/344007/41178]  |
| 专题 | 中国科学院广州能源研究所 |
| 通讯作者 | Wang, Haiyong; Ma, Longlong |
| 作者单位 | 1.Univ Sci & Technol China, Dept Thermal Sci & Energy Engn, Hefei 230026, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 3.Southeast Univ, Sch Energy & Environm, Key Lab Energy Thermal Convers & Control, Minist Educ, Nanjing 210096, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Bin,Chen, Peili,Zhu, Tianhan,et al. Direct Hydrogenation of Furfural to 2-Methyltetrahydrofuran over an Efficient Cu-Pd/HY Bimetallic Catalyst[J]. ENERGY & FUELS,2024,38(6):5303-5313. |
| APA | Yang, Bin.,Chen, Peili.,Zhu, Tianhan.,Dong, Guilin.,Wang, Haiyong.,...&Ma, Longlong.(2024).Direct Hydrogenation of Furfural to 2-Methyltetrahydrofuran over an Efficient Cu-Pd/HY Bimetallic Catalyst.ENERGY & FUELS,38(6),5303-5313. |
| MLA | Yang, Bin,et al."Direct Hydrogenation of Furfural to 2-Methyltetrahydrofuran over an Efficient Cu-Pd/HY Bimetallic Catalyst".ENERGY & FUELS 38.6(2024):5303-5313. |
入库方式： OAI收割
来源：广州能源研究所
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